Skip to Content
Merck
CN

331023

Nonafluoro-tert-butyl alcohol

99%

Synonym(s):

1,1,1,3,3,3-Hexafluoro-2-trifluoromethyl-2-propanol, Perfluoro-tert-butyl alcohol

Sign In to View Organizational & Contract Pricing

Select a Size

About This Item

Linear Formula:
(CF3)3COH
CAS Number:
2378-02-1
Molecular Weight:
236.04
Beilstein:
1841640
EC Number:
219-157-3
MDL number:
MFCD00042092
UNSPSC Code:
12352100
PubChem Substance ID:
24859928
NACRES:
NA.05

Key Documents

View All Documentation
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist

vapor pressure

5.19 psi ( 20 °C)

Assay

99%

form

liquid

refractive index

n20/D 1.3 (lit.)

bp

45 °C (lit.)

density

1.693 g/mL at 25 °C (lit.)

functional group

fluoro
hydroxyl

SMILES string

OC(C(F)(F)F)(C(F)(F)F)C(F)(F)F

InChI

1S/C4HF9O/c5-2(6,7)1(14,3(8,9)10)4(11,12)13/h14H

InChI key

XZNOAVNRSFURIR-UHFFFAOYSA-N

Looking for similar products? Visit Product Comparison Guide

Related Categories

General description

Nonafluoro-tert-butyl alcohol is also referred as perfluorotertiarybutanol and ′artificial blood′.

Application

Nonafluoro-tert-butyl alcohol was employed as a precursor for the preparation of appropriate bis(polyfluoroalkoxymethyl)carbinols and their corresponding mesylates.

Pictograms

Skull and crossbones
GHS06

Signal Word

Danger

Hazard Statements

H315,H319,H331,H335

Hazard Classifications

Acute Tox. 3 Inhalation - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number
BCCP0560
BCCM4308
BCCL5212
BCCK9607
BCCH2511

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Huan Meng et al.
Organic letters, 21(13), 5206-5210 (2019-06-30)
A highly efficient method to incorporate the nonafluoro- tert-butoxy group into various arenes is developed. This C-O cross-coupling reaction proceeds smoothly in the absence of transition-metal catalyst with good functional group tolerance and scalability. In comparison with the conventional approach
Greener fluorous chemistry: Convenient preparation of new types of 'CF< sub> 3</sub>-rich'secondary alkyl mesylates and their use for the synthesis of azides, amines, imidazoles and imidazolium salts
Nemes A, et al.
Journal of Fluorine Chemistry, 131(12), 1368-1376 (2010)
Cyclization and rearrangement products from coupling reactions between terminal< i> o</i>-alkynylphenols or< i> o</i>-ethynyl (hydroxymethyl) benzene and 6-halopurines.
Berg TC, et al.
Tetrahedron, 62(25), 6121-6131 (2006)
Maxime Bourguignon et al.
Macromolecular rapid communications, 42(3), e2000482-e2000482 (2020-10-14)
Polyurethane hydrogels are attractive materials finding multiple applications in various sectors of prime importance; however, they are still prepared by the toxic isocyanate chemistry. Herein the facile and direct preparation in water at room temperature of a large palette of

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service