Skip to Content
Merck
CN

333239

Titanium(IV) fluoride

powder and chunks

Synonym(s):

Titanium tetrafluoride, Titanium fluoride

Sign In to View Organizational & Contract Pricing.

Select a Size

Change View

About This Item

Linear Formula:
TiF4
CAS Number:
Molecular Weight:
123.86
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
232-017-6
MDL number:
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist


Product Name

Titanium(IV) fluoride,

form

powder and chunks

Quality Level

reaction suitability

core: titanium, reagent type: catalyst

density

2.798 g/mL at 25 °C (lit.)

SMILES string

F[Ti](F)(F)F

InChI

1S/4FH.Ti/h4*1H;/q;;;;+4/p-4

InChI key

XROWMBWRMNHXMF-UHFFFAOYSA-J

Application

Used for preparation of glycosyl fluorides; glycosylation; preparation of fluorohydrins; addition of carbanions to aldehydes and imines.
Catalyst for:
  • Chemoselective synthesis and deprotection of geminal diacetates of aldehydes


pictograms

CorrosionExclamation mark

signalword

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges



Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library


Articles

Titanium dioxide applications: Semiconducting material characteristics and diverse functionalities.


Annette Wiegand et al.
Archives of oral biology, 54(8), 790-795 (2009-06-02)
This study aimed to analyse and compare the protective effect of buffered (pH 3.5) and native (pH 1.2) TiF(4) in comparison to NaF solutions of same pH on dentin erosion. Bovine samples were pretreated with 1.50% TiF(4) or 2.02% NaF
Annette Wiegand et al.
Archives of oral biology, 55(3), 223-228 (2010-01-20)
This in situ study aimed to analyse the impact of different tetrafluorides (TiF(4), ZrF(4) and HfF(4)) and AmF on erosion and erosion plus abrasion of enamel and dentin. Ten volunteers took part in this crossover and double-blind study performed in
Thomas R Gordon et al.
Journal of the American Chemical Society, 134(15), 6751-6761 (2012-03-27)
Control over faceting in nanocrystals (NCs) is pivotal for many applications, but most notably when investigating catalytic reactions which occur on the surfaces of nanostructures. Anatase titanium dioxide (TiO(2)) is one of the most studied photocatalysts, but the shape dependence



Global Trade Item Number

SKUGTIN
333239-100G04061826737170
333239-10G04061826737187