333239
Titanium(IV) fluoride
powder and chunks
Synonym(s):
Titanium tetrafluoride, Titanium fluoride
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About This Item
Linear Formula:
TiF4
CAS Number:
Molecular Weight:
123.86
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
232-017-6
MDL number:
Product Name
Titanium(IV) fluoride,
form
powder and chunks
Quality Level
reaction suitability
core: titanium, reagent type: catalyst
density
2.798 g/mL at 25 °C (lit.)
SMILES string
F[Ti](F)(F)F
InChI
1S/4FH.Ti/h4*1H;/q;;;;+4/p-4
InChI key
XROWMBWRMNHXMF-UHFFFAOYSA-J
Application
Used for preparation of glycosyl fluorides; glycosylation; preparation of fluorohydrins; addition of carbanions to aldehydes and imines.
Catalyst for:
- Chemoselective synthesis and deprotection of geminal diacetates of aldehydes
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B
Storage Class
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
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Articles
Titanium dioxide applications: Semiconducting material characteristics and diverse functionalities.
Annette Wiegand et al.
Oral health & preventive dentistry, 8(2), 159-164 (2010-07-01)
The present review summarises the effects of titanium tetrafluoride (TiF(4)) on the development and progression of carious and erosive lesions. The mode of action of TiF(4) is due to the formation of an acid-stable surface layer, which provides mechanical protection
A Wiegand et al.
Caries research, 43(4), 269-277 (2009-05-15)
This study aimed to analyse and compare the protective effect of buffered (pH 3.5) and native (pH 1.2) TiF(4) in comparison with NaF solutions on enamel erosion. Bovine samples were pretreated with 1.50% TiF(4) or 2.02% NaF (both 0.48 M
Shimizu, M.; Morita, A.; Kaga, T.
Tetrahedron Letters, 40, 8401-8401 (1999)
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 333239-100G | 04061826737170 |
| 333239-10G | 04061826737187 |