333646
1,13-Tetradecadiene
90%
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About This Item
Linear Formula:
CH2=CH(CH2)10CH=CH2
CAS Number:
Molecular Weight:
194.36
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
244-687-7
Beilstein/REAXYS Number:
1741459
MDL number:
Assay:
90%
Form:
liquid
InChI key
XMRSTLBCBDIKFI-UHFFFAOYSA-N
InChI
1S/C14H26/c1-3-5-7-9-11-13-14-12-10-8-6-4-2/h3-4H,1-2,5-14H2
SMILES string
C=CCCCCCCCCCCC=C
assay
90%
form
liquid
Quality Level
bp
131 °C/17 mmHg (lit.)
density
0.849 g/mL at 25 °C (lit.)
functional group
allyl
Related Categories
General description
1,13-Tetradecadiene is an α-diolefin. Polymerization of 1,13-tetradecadiene using aluminum triisobutyl-titanium tetrachloride was reported.
Application
1,13-Tetradecadiene was grafted to hydrogenated B-doped silicon (100) surfaces. It was used in the synthesis of naturally occurring, biologically active pyridine alkaloids theonelladins C and D, niphatesine C and xestamine D.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
10 - Combustible liquids
wgk
WGK 3
flash_point_f
217.4 °F - closed cup
flash_point_c
103 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
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Polymerization of Higher a-Diolefins with Metal Alkyl Coordination Catalysts1.
Marvel CS and Garrison Jr WE.
Journal of the American Chemical Society, 81(17), 4737-4744 (1959)
Kotohiro Nomura et al.
Polymers, 12(1) (2019-12-22)
Copolymerizations of 1-decene (DC) with 1,9-decadiene (DCD), 1-dodecene (DD) with 1,11-dodecadiene (DDD), and 1-tetradecene (TD) with 1,13-tetradecadiene (TDD), using Cp*TiMe2(O-2,6-iPr2C6H3) (1)-[Ph3C][B(C6F5)4] (borate) catalyst in the presence of AliBu3/Al(n-C8H17)3 proceeded in a quasi-living manner in n-hexane at -30 to -50 °C
Monolayers of simple organic molecules on silicon studied by surface tools.
Scandurra A, et al.
Surface and Interface Analysis : SIA, 34(1), 777-777 (2002)
Synthesis of pyridine alkaloids via Pd-catalyzed coupling of 3-iodopyridine, 1, ?-dienes and nitrogen nucleophiles.
Larock RC and Wang Y.
Tetrahedron Letters, 43(1), 21-23 (2002)
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