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333646

1,13-Tetradecadiene

Name: 1,13-Tetradecadiene
Brand: ALDRICH

90%

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About This Item

Linear Formula:

CH₂=CH(CH₂)₁₀CH=CH₂

CAS Number:

21964-49-8

Molecular Weight:

194.36

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24860161

EC Number:

244-687-7

Beilstein/REAXYS Number:

1741459

MDL number:

MFCD00014941

Assay:

90%

Form:

liquid

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Properties

Quality Level

100

assay

90%

form

liquid

refractive index

n20/D 1.443 (lit.)

bp

131 °C/17 mmHg (lit.)

density

0.849 g/mL at 25 °C (lit.)

functional group

allyl

SMILES string

C=CCCCCCCCCCCC=C

InChI

1S/C14H26/c1-3-5-7-9-11-13-14-12-10-8-6-4-2/h3-4H,1-2,5-14H2

InChI key

XMRSTLBCBDIKFI-UHFFFAOYSA-N

Description

General description

1,13-Tetradecadiene is an α-diolefin. Polymerization of 1,13-tetradecadiene using aluminum triisobutyl-titanium tetrachloride was reported.

Application

1,13-Tetradecadiene was grafted to hydrogenated B-doped silicon (100) surfaces. It was used in the synthesis of naturally occurring, biologically active pyridine alkaloids theonelladins C and D, niphatesine C and xestamine D.

pictograms

GHS07

signalword

Warning

hcodes

H315,H319,H335

pcodes

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

217.4 °F - closed cup

flash_point_c

103 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

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Monolayers of simple organic molecules on silicon studied by surface tools.

Scandurra A, et al.

Surface and Interface Analysis : SIA, 34(1), 777-777 (2002)

Synthesis of pyridine alkaloids via Pd-catalyzed coupling of 3-iodopyridine, 1, ?-dienes and nitrogen nucleophiles.

Larock RC and Wang Y.

Tetrahedron Letters, 43(1), 21-23 (2002)

Synthesis of Ultrahigh Molecular Weight Polymers Containing Reactive Functionality with Low PDIs by Polymerizations of Long-Chain α-Olefins in the Presence of Their Nonconjugated Dienes by Cp*TiMe2(O-2,6-iPr2C6H3)-Borate Catalyst.

Kotohiro Nomura et al.

Polymers, 12(1) (2019-12-22)

Copolymerizations of 1-decene (DC) with 1,9-decadiene (DCD), 1-dodecene (DD) with 1,11-dodecadiene (DDD), and 1-tetradecene (TD) with 1,13-tetradecadiene (TDD), using Cp*TiMe2(O-2,6-iPr2C6H3) (1)-[Ph3C][B(C6F5)4] (borate) catalyst in the presence of AliBu3/Al(n-C8H17)3 proceeded in a quasi-living manner in n-hexane at -30 to -50 °C

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Global Trade Item Number

SKU	GTIN
333646-1G	04061826737385