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Merck
CN

338729

Sigma-Aldrich

Vinylbenzyl chloride

97%, Mixture of 2, 3- and 4-isomers, stabilized

Synonym(s):

(Chloromethyl)styrene

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About This Item

Linear Formula:
H2C=CHC6H4CH2Cl
CAS Number:
Molecular Weight:
152.62
Beilstein:
2204384
EC Number:
MDL number:
UNSPSC Code:
12162002
PubChem Substance ID:
NACRES:
NA.23
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vapor density

5.3 (vs air)

vapor pressure

1 mmHg ( 56.1 °C)

Assay

97%

form

liquid

autoignition temp.

1139 °F

refractive index

n20/D 1.572 (lit.)

bp

229 °C (lit.)

density

1.074 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

ClCc1ccc(C=C)cc1.ClCc2cccc(C=C)c2

InChI

1S/2C9H9Cl/c1-2-8-3-5-9(7-10)6-4-8;1-2-8-4-3-5-9(6-8)7-10/h2*2-6H,1,7H2

InChI key

QSDACPJNNYTTDP-UHFFFAOYSA-N

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Application

  • A preliminary study on the synthesis of poly (vinylbenzyl chloride) with different solvents: This research is crucial for material scientists interested in the polymerization process and the properties of the resulting polymers (Mathew et al., 2021).
  • RAFT homopolymerization of vinylbenzyl chloride: This study discusses the controlled polymerization of vinylbenzyl chloride, which could be of interest to academia looking to develop functionalized polymers for various applications (Sato et al., 2014).
  • Quaternized poly (styrene-co-vinylbenzyl chloride) anion exchange membranes for alkaline water electrolyzers: Relevant for material science, this research explores the use of polymer membranes in energy applications, particularly in electrolyzers (Vengatesan et al., 2015).
  • Polybenzimidazole-crosslinked poly (vinylbenzyl chloride) with quaternary 1, 4-diazabicyclo (2.2. 2) octane groups as high-performance anion exchange membrane: This paper would interest those in material science and academia by exploring high-performance materials for fuel cell applications (Lu et al., 2015).
  • Preparation and characterization of sulfur-vinylbenzyl chloride polymer under optimized reaction conditions using inverse vulcanization: This research is significant for those interested in novel polymer synthesis techniques and their potential applications (Abbasi et al., 2021).

Pictograms

Skull and crossbonesEnvironment

Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point(F)

213.8 °F - closed cup

Flash Point(C)

101 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Véronique Lenoble et al.
Journal of colloid and interface science, 448, 473-481 (2015-03-17)
Three novel Ni(II)-Ion-Imprinted Polymer (IIP) were synthesized by precipitation polymerization of ethylene glycol dimethacrylate (crosslinker) with a complex of nickel(II) and vinylbenzyl iminodiacetic acid (VbIDA). The three IIPs were prepared with various mixtures of porogen solvents: methanol, methanol/2-methoxyethanol and methanol/acetonitrile

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