339725
Chloromethane solution
1.0 M in tert-butyl methyl ether, anhydrous
Synonym(s):
Methyl chloride
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About This Item
Empirical Formula (Hill Notation):
CH3Cl
CAS Number:
Molecular Weight:
50.49
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Form:
liquid
InChI
1S/CH3Cl/c1-2/h1H3
SMILES string
CCl
InChI key
NEHMKBQYUWJMIP-UHFFFAOYSA-N
grade
anhydrous
form
liquid
concentration
1.0 M in tert-butyl methyl ether
impurities
<0.005% water
density
0.765 g/mL at 25 °C
functional group
alkyl halide, chloro
storage temp.
2-8°C
Quality Level
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General description
Radiolysis of aqueous solutions of chloromethanes was performed with γ-rays. Dechlorination of chloromethane on iron and palladium-iron bimetallic surface in aqueous systems has been reported.
Packaging
Supplied in a Sure/Pac™ cylinder and has a 1/4-turn bronze ball valve with a female 1/4" NPT outlet thread (Z122661) installed. Before using the cylinder, ensure that the valve is closed, then remove carbon steel plug that seals the outlet valve.
Compatible with the following:
Compatible with the following:
- Aldrich® Sure/Pac™ station for liquefied gases Z566446
- PTFE Sealing tape Z104388 or Z221880
- Straight septum-inlet adapter Z118141 with septa Z565687 or Z565695
Legal Information
Aldrich is a registered trademark of Sigma-Aldrich Co. LLC
Sure/Pac is a trademark of Sigma-Aldrich Co. LLC
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Danger
Hazard Classifications
Carc. 2 - Flam. Liq. 2 - Ozone 1 - Repr. 2 - Skin Irrit. 2
Storage Class
3 - Flammable liquids
wgk
WGK 2
flash_point_f
-29.2 °F - closed cup
flash_point_c
-34 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Regulatory Information
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Dechlorination of chloromethanes on iron and palladium-iron bimetallic surface in aqueous systems.
Wan C, et al
Environmental Toxicology and Chemistry / Setac, 18(6), 1091-1096 (1999)
L El Khoury et al.
The Journal of chemical physics, 136(2), 024319-024319 (2012-01-21)
We present a combined experimental and theoretical study of isolated CH(3)Cl molecules using resonant inelastic x-ray scattering (RIXS). The high-resolution spectra allow extraction of information about nuclear dynamics in the core-excited molecule. Polarization-resolved RIXS spectra exhibit linear dichroism in the
Xiaofeng Tang et al.
The Journal of chemical physics, 136(3), 034304-034304 (2012-01-28)
Utilizing threshold photoelectron-photoion coincidence (TPEPICO) velocity imaging, dissociation of state-selected CH(3)Cl(+) ions was investigated in the excitation energy range of 11.0-18.5 eV. TPEPICO time-of-flight mass spectra and three-dimensional time-sliced velocity images of CH(3)(+) dissociated from CH(3)Cl(+)(A(2)A(1) and B(2)E) ions were
High dose radiolysis of aqueous solutions of chloromethanes: Importance in the storage of radioactive organic wastes.
Rajesh P, et al.
Journal of Nuclear Materials, 361(1), 10-17 (2007)
Leonie Derendorp et al.
Chemosphere, 87(5), 483-489 (2012-01-10)
Methyl chloride (CH(3)Cl) is the most abundant natural chlorine containing compound in the atmosphere, and responsible for a significant fraction of stratospheric ozone destruction. Understanding the global CH(3)Cl budget is therefore of great importance. However, the strength of the individual
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