339806
3,5-Dimethoxybenzylamine
97%
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About This Item
Linear Formula:
(CH3O)2C6H3CH2NH2
CAS Number:
Molecular Weight:
167.21
UNSPSC Code:
12352100
PubChem Substance ID:
MDL number:
Assay:
97%
Form:
solid
InChI
1S/C9H13NO2/c1-11-8-3-7(6-10)4-9(5-8)12-2/h3-5H,6,10H2,1-2H3
SMILES string
COc1cc(CN)cc(OC)c1
InChI key
YGZJTYCCONJJGZ-UHFFFAOYSA-N
assay
97%
form
solid
refractive index
n20/D 1.542 (lit.)
bp
94-96 °C/0.1 mmHg (lit.)
mp
35-37 °C (lit.)
density
1.106 g/mL at 25 °C (lit.)
Quality Level
General description
3,5-Dimethoxybenzylamine was prepared by LiAlH4-reduction of 3,5-dimethoxybenzaldoxime.
Application
3,5-Dimethoxybenzylamine was used in the preparation of trisammonium tris(hexafluoro phosphate) salt. It was also used in the synthesis of well defined, homogeneous [n]rotaxanes (n up to 11) by a template-directed thermodynamic clipping approach.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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Jishan Wu et al.
Proceedings of the National Academy of Sciences of the United States of America, 104(44), 17266-17271 (2007-10-20)
In this article, we report on the efficient synthesis of well defined, homogeneous [n]rotaxanes (n up to 11) by a template-directed thermodynamic clipping approach. By employing dynamic covalent chemistry in the form of reversible imine bond formation, [n]rotaxanes with dialkylammonium
Methoxy-substituted benzyl isothiocyanates and N-benzyl thioureas.
Bach ERIK and Kjaer A.
Acta Chemica Scandinavica, 25(7) (1971)
The exclusivity of multivalency in dynamic covalent processes.
Jovica D Badjić et al.
Angewandte Chemie (International ed. in English), 43(25), 3273-3278 (2004-06-24)
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