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Dimethyl methylmalonate

Name: Dimethyl methylmalonate
Brand: ALDRICH

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About This Item

Linear Formula:

CH₃CH(CO₂CH₃)₂

CAS Number:

609-02-9

Molecular Weight:

146.14

UNSPSC Code:

12352100

PubChem Substance ID:

24860790

EC Number:

210-173-6

MDL number:

MFCD00075185

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Properties

vapor pressure

0.2 mmHg ( 20 °C)

assay

99%

refractive index

n20/D 1.414 (lit.)

bp

176-177 °C (lit.)

density

1.098 g/mL at 25 °C (lit.)

SMILES string

COC(=O)C(C)C(=O)OC

InChI

1S/C6H10O4/c1-4(5(7)9-2)6(8)10-3/h4H,1-3H3

InChI key

LRBPFPZTIZSOGG-UHFFFAOYSA-N

Description

General description

Dimethyl methylmalonate is an ester. Microwave-enhanced Pd(0)/acetic acid catalyzed allylation of C, N and O-nucleophiles with dimethyl methylmalonate has been reported.

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

168.8 °F - closed cup

flash_point_c

76 °C - closed cup

ppe

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)

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Microwave-enhanced Pd (0)/acetic acid catalyzed allylation reactions of C, N, and O -pronucleophiles with alkynes.

Patil NT, et al.

Tetrahedron Letters, 45(46), 8497-8499 (2004)