341096
Succinimidyl 2,2,2-trichloroethyl carbonate
98%
Synonym(s):
N-(2,2,2-Trichloroethoxycarbonyloxy)succinimide
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About This Item
Empirical Formula (Hill Notation):
C7H6Cl3NO5
CAS Number:
Molecular Weight:
290.49
UNSPSC Code:
12352100
PubChem Substance ID:
MDL number:
InChI
1S/C7H6Cl3NO5/c8-7(9,10)3-15-6(14)16-11-4(12)1-2-5(11)13/h1-3H2
SMILES string
ClC(Cl)(Cl)COC(=O)ON1C(=O)CCC1=O
InChI key
WBZXNGAFYBGQFE-UHFFFAOYSA-N
assay
98%
mp
111-113 °C (lit.)
storage temp.
2-8°C
Application
Succinimidyl 2,2,2-trichloroethyl carbonate was used in the synthesis of:
- methyl [phenyl 5-(2,2,2-trichloroethoxycarbonylamino)-3,5-dideoxy-2-thio-β-D-glycero-D-galacto-2-nonulopyranosid]-onate
- phenyl 3,4-di-O-benzyl-6-O-(tert-butyl-dimethyl-silyl)-1-selanyl-2-(2,2,2-trichloroethoxycarbonylamine)-β-D-galactopyranoside
signalword
Warning
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
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Chien-Tai Ren et al.
The Journal of organic chemistry, 67(4), 1376-1379 (2002-02-16)
The preparation of a disaccharide 2, Neu5Ac-alpha-(2-->5)Neu5Gc having a alpha-benzyl protecting group at the reducing end, by the coupling of the easily accessible building units 4 and 5 is described. Subsequent deprotection of the coupling adduct led to the isolation
Chien-Tai Ren et al.
The Journal of organic chemistry, 72(14), 5427-5430 (2007-06-21)
Synthesis of a tetrasaccharide glycosyl glycerol, the core structure of glycoglycerolipid from Meiothermus taiwanensis ATCC BAA-400, was described. A one-pot glycosylation with three components was employed as a key step.
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