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About This Item
Linear Formula:
[[(CH3)2CH]2N]2PCl
CAS Number:
Molecular Weight:
266.79
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352001
MDL number:
Quality Segment
assay
≥95.0%
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling
mp
100-104 °C (lit.)
functional group
phosphine
SMILES string
CC(C)N(C(C)C)P(Cl)N(C(C)C)C(C)C
InChI
1S/C12H28ClN2P/c1-9(2)14(10(3)4)16(13)15(11(5)6)12(7)8/h9-12H,1-8H3
InChI key
FEHUTHGOLLQBNW-UHFFFAOYSA-N
Application
Bis(diisopropylamino)chlorophosphine has been used in the synthesis of tert-butyl tetraisopropylphosphorodiamidite ligand for palladium-catalyzed Buchwald–Hartwig amination reaction.
It is also can be used to synthesize:
It is also can be used to synthesize:
- acyclic N-phosphonio imine catalyst for selective epoxidations
- boryl-substituted methylenephosphonium derivatives
Other Notes
Contains varying amounts of diisopropylamine hydrochloride
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
Storage Class
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
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