341363
(1R,2S,5R)-(+)-5-Methyl-2-(1-methyl-1-phenylethyl)cyclohexyl chloroacetate
99%
Synonym(s):
(+)-8-Phenylmenthyl chloroacetate
Sign In to View Organizational & Contract Pricing
Select a Size
About This Item
Empirical Formula (Hill Notation):
C18H25ClO2
CAS Number:
Molecular Weight:
308.84
MDL number:
UNSPSC Code:
12352101
PubChem Substance ID:
NACRES:
NA.22
Assay
99%
form
solid
optical activity
[α]25/D +22°, c = 1.2 in carbon tetrachloride
mp
82-84 °C (lit.)
functional group
chloro
ester
phenyl
SMILES string
C[C@@H]1CC[C@H]([C@@H](C1)OC(=O)CCl)C(C)(C)c2ccccc2
InChI
1S/C18H25ClO2/c1-13-9-10-15(16(11-13)21-17(20)12-19)18(2,3)14-7-5-4-6-8-14/h4-8,13,15-16H,9-12H2,1-3H3/t13-,15-,16-/m1/s1
InChI key
GYWWQECFQIGECM-FVQBIDKESA-N
Application
(1R,2S,5R)-(+)-5-Methyl-2-(1-methyl-1-phenylethyl)cyclohexyl chloroacetate may be used in the synthesis of (-)-8-phenylmenthol, (+)-8-phenylmenthyl isocyanoacetate and (+)-cularine.
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
新产品
This item has
Choose from one of the most recent versions:
Already Own This Product?
Find documentation for the products that you have recently purchased in the Document Library.
1R, 2S, 5R)-5-Methyl-2-(1-methyl-1-phenylethyl) cyclohexyl chloroacetate.
Sieder F, et al.
Acta Crystallographica Section E, Structure Reports Online, 62(6), o2291-o2292 (2006)
A diastereoselective radical cyclisation approach to pyroglutamates.
Goodall K and Parsons AF.
Tetrahedron Letters, 38(3), 491-494 (1997)
Diastereoselective synthesis of cularine alkaloids via enium ions and an easy entry to isoquinolines by aza-Wittig electrocyclic ring closure.
Rodrigues JAR, et al.
The Journal of Organic Chemistry, 69(9), 2920-2928 (2004)
An efficient synthesis of (+)-8-phenylmenthyl isocyanoacetate.
Solladie-Cavallo A and Quazzotti S.
Tetrahedron Asymmetry, 3(1), 39-42 (1992)
Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.
Contact Technical Service