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344087

(−)-(R)-N,N-Dimethyl-1-[(S)-1′,2-bis(diphenylphosphino)ferrocenyl]ethylamine

95%

Synonym(s):

[R,R]-1-[1-Dimethylaminoethyl]-1′,2-bis[diphenylphosphino]ferrocene

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About This Item

Empirical Formula (Hill Notation):
C38H37FeNP2
CAS Number:
74311-56-1
Molecular Weight:
625.50
NACRES:
NA.22
PubChem Substance ID:
24861223
UNSPSC Code:
12352005
MDL number:
MFCD00075284
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assay

95%

form

powder

optical activity

[α]20/D −350°, c = 0.5 in chloroform

mp

143-144 °C (lit.)

SMILES string

[Fe].[CH]1[CH][CH][C]([CH]1)P(c2ccccc2)c3ccccc3.C[C@H]([C]4[CH][CH][CH][C]4P(c5ccccc5)c6ccccc6)N(C)C

InChI

1S/C21H23NP.C17H14P.Fe/c1-17(22(2)3)20-15-10-16-21(20)23(18-11-6-4-7-12-18)19-13-8-5-9-14-19;1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;/h4-17H,1-3H3;1-14H;/t17-;;/m1../s1

InChI key

VUJPTJYMSBMZOZ-ZEECNFPPSA-N

Application

Ligand used in the enantioselective silylation of allylic chlorides.

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
00831ME
02430HW
01926BD
15514KI
13524CG

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Matsumoto, Y. et al.
Organometallics, 12, 4051-4051 (1993)

Global Trade Item Number

SKUGTIN
344087-100MG04061833279571