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Merck
CN

345288

Poly(tetrahydrofuran)

average Mn ~650

Synonym(s):

Terathane® 650 polyether glycol, poly(tetramethylene ether), α-Hydro-ω-hydroxypoly(oxy-1,4-butanediyl), Poly(1,4-butanediol), polyTHF

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About This Item

Linear Formula:
H(OCH2CH2CH2CH2)nOH
CAS Number:
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12162002
MDL number:
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vapor pressure

<0.01 mmHg ( 25 °C), <1 mmHg ( 20 °C)

mol wt

average Mn ~650

contains

0.05-0.07% BHT as stabilizer

refractive index

n20/D 1.465

mp

11-19 °C

density

0.978 g/mL at 25 °C

SMILES string

OCCCCO

InChI

1S/C8H18O2/c1-3-5-6-10-8(4-2)7-9/h8-9H,3-7H2,1-2H3/t8-/m0/s1

InChI key

BJZYYSAMLOBSDY-QMMMGPOBSA-N

General description

Poly(tetrahydrofuran) (PTHF) is a highly flexible hydrophobic polymer widely used in the synthesis of thermoplastic elastomers such as polyesters and polyurethanes. The addition of PHTF imparts abrasion resistance, hydrolytic stability, and attractive dynamic properties to the material. This polymer can also be used to prepare block copolymers, end-functional star polymers, amphiphilic conetworks, and thermogels.

Application

Poly(tetrahydrofuran) can be used as a precursor to synthesize epoxy-urethane polymer networks. It can also be used as a diol comonomer to synthesize block copolymers, such as poly-(alkyleneterephthalаte-co-alkylenephosphate).

Legal Information

Terathane is a registered trademark of Invista North America S.a.r.l.


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pictograms

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signalword

Warning

hcodes

Hazard Classifications

Acute Tox. 4 Oral - STOT SE 3

target_organs

Respiratory system

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

474.8 °F - Cleveland open cup

flash_point_c

246 °C - Cleveland open cup

ppe

dust mask type N95 (US), Eyeshields, Gloves



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Cross-linked poly(tetrahydrofuran) as promising sorbent for organic solvent/oil spill
Ilker Yati, et al.
Journal of Hazardous Materials, 309, 210-218 (2016)
Novel thermally-reversible epoxy-urethane networks
Viorica Gaina, et al.
Designed Monomers and Polymers, 15, 63-73 (2012)
Synthesis of poly-(alkyleneterephthal?te-co-alkylenephosphate) s and their blends with a linear polyurethane
V Mitova, et al.
Bulgarian Chemical Communications, 129-129 (2020)



Global Trade Item Number

SKUGTIN
345288-18L04061837797286
345288-3L04061826760529
345288-1L04061826760505
345288-25ML04061826760512