Key Documents

View All Documentation

345857

Tetrabutylammonium chloride hydrate

Name: Tetrabutylammonium chloride hydrate
Brand: ALDRICH

98%, solid

Synonym(s):

TBAC hydrate

Select a Size

Change View

About This Item

Linear Formula:

(CH₃CH₂CH₂CH₂)₄N(Cl) · xH₂O

CAS Number:

37451-68-6

Molecular Weight:

277.92

UNSPSC Code:

12352116

PubChem Substance ID:

24861355

NACRES:

NA.22

EC Number:

214-195-7

MDL number:

MFCD00149970

Beilstein/REAXYS Number:

3765327

Technical Service

Need help? Our team of experienced scientists is here for you.

Let Us Assist

Properties

Product Name

Tetrabutylammonium chloride hydrate, 98%

Quality Level

200

assay

98%

form

solid

reaction suitability

core: ammonium

mp

41-44 °C (lit.)

SMILES string

[Cl-].[N+](CCCC)(CCCC)(CCCC)CCCC.O

InChI

1S/C16H36N.ClH.H2O/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;;/h5-16H2,1-4H3;1H;1H2/q+1;;/p-1

InChI key

FODWRUPJCKASBN-UHFFFAOYSA-M

Description

Application

Tetrabutylammonium chloride hydrate can be used:

As an additive in palladium-catalyzed cross-coupling reaction of heteroaromatic carboxylic acids with aryl bromides.
To enhance the reactivity of palladium-catalyzed arylation of methyl acrylates.
In derivatization of bis(spirodienone) calixarene having exocyclic double bonds to its chloro derivative.

Tetrabutylammonium chloride (TBAC) hydrate has been used as a phase transfer catalyst in the synthesis of fullerenols and in Heck-type palladium-catalyzed vinylation of organic halides in water. TBAC hydrate has also been reported to be a promising candidate for cool energy storage material.

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Phase equilibrium of ionic semiclathrate hydrates formed with tetrabutylammonium bromide and tetrabutylammonium chloride.

Sato K, et al.

Fluid Phase Equilibria, 337, 115-118 (2013)

Unexpected intermolecular Pd-catalyzed cross-coupling reaction employing heteroaromatic carboxylic acids as coupling partners

Forgione P, et al.

Journal of the American Chemical Society, 128(35), 11350-11351 (2006)

On the efficiency of tetraalkylammonium salts in Heck type reactions

Jeffery T

Tetrahedron, 52(30), 10113-10130 (1996)

View All Related Papers

Global Trade Item Number

SKU	GTIN
345857-100G	04061833002346
345857-5G	04061826760925
345857-25G	04061826760918