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Merck
CN

346462

Zirconium(IV) oxynitrate hydrate

technical grade

Synonym(s):

Zirconyl nitrate hydrate

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About This Item

Linear Formula:
ZrO(NO3)2 · xH2O
CAS Number:
14985-18-3
Molecular Weight:
231.23 (anhydrous basis)
EC Number:
237-529-3
MDL number:
MFCD00149896
UNSPSC Code:
12352302
PubChem Substance ID:
24861411
NACRES:
NA.23
Grade:
technical grade
Form:
powder

Key Documents

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grade

technical grade

form

powder

composition

Degree of hydration, ~6

reaction suitability

core: zirconium

concentration

25-30% Zr (after ignition to oxide, gravimetric)

SMILES string

O=[Zr++].[H]O[H].[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/2NO3.H2O.O.Zr/c2*2-1(3)4;;;/h;;1H2;;/q2*-1;;;+2

InChI key

BGMQNYCWALSARE-UHFFFAOYSA-N

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General description

Zirconium(IV) oxynitrate hydrate is an inorganic salt primarily used as a precursor for the synthesis of zirconium nanoparticles, to fabricate Li-ion batteries, and as a catalyst in various chemical reactions.

Application

Zirconium(IV) oxynitrate hydrate can be used:
  • As a starting material to prepare electrolytes for Li-ion batteries.
  • For the surface modification of cathodes, to enhance the electrochemical properties of all-solid-state batteries.
  • As a precursor for surfactant-free synthesis of zirconia nanostructures.
It can also be used as a catalyst for:
  • Regiospecific alcoholysis and aminolysis of epoxides.
  • One-pot synthesis and oxidation of bis- and tris(indolyl)methanes into conjugated chromophores.

Signal Word

Danger

Hazard Statements

H272,H302,H314

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Ox. Sol. 2 - Skin Corr. 1B

Supplementary Hazards

EUH071

Storage Class Code

5.1B - Oxidizing hazardous materials

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

危险化学品
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Certificates of Analysis (COA)

Lot/Batch Number
MKCZ3719
MKCX7328
MKCX1467
MKCX1469
MKCT6081

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Mild regiospecific alcoholysis and aminolysis of epoxides catalyzed by zirconium(IV) oxynitrate
Sandip S. Shinde, et al.
Tetrahedron Letters, 56, 5916-5919 (2015)
Zirconia Nanostructures: Novel Facile Surfactant-Free Preparation and Characterization
Sahar Zinatloo-Ajabshir, et al.
International Journal of Applied Ceramic Technology, 13, 108-115 (2016)
Zirconium(IV)-catalyzed one-pot synthesis and oxidation of bis- and tris(indolyl)methanes into conjugated chromophores as new pH indicators or calorimetric chemosensors for transition metals
Alireza Khorshidi, et al.
Tetrahedron Letters, 55, 3873-3877 (2014)
Enhanced electrochemical properties of all-solid-state batteries using a surface-modified LiNi 0.6 Co 0.2 Mn 0.2 O 2 Cathode
Chung Bum Lim, et al.
Journal of Electrochemical Science and Technology, 11, 411-420 (2020)
The Structure and Electrical Properties of Li7La3Zr1.0Sn1.0O12 as Electrolyte Material for Li-ion Batteries
Siti Nur Adlina Norazman, et al.
Advances in Science and Technology, 118, 27-32 (2022)

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