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Merck
CN

357340

Rhodium

foil, thickness 0.025 mm, 99.9% trace metals basis

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About This Item

Empirical Formula (Hill Notation):
Rh
CAS Number:
7440-16-6
Molecular Weight:
102.91
NACRES:
NA.23
PubChem Substance ID:
24861906
UNSPSC Code:
12352300
EC Number:
231-125-0
MDL number:
MFCD00011201

Key Documents

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InChI key

MHOVAHRLVXNVSD-UHFFFAOYSA-N

InChI

1S/Rh

SMILES string

[Rh]

assay

99.9% trace metals basis

form

foil

resistivity

4.33 μΩ-cm, 20°C

thickness

0.025 mm

bp

3727 °C (lit.)

mp

1966 °C (lit.)

density

12.41 g/cm3 (lit.)

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Preparation Note

190 mg = 25 × 25 mm

Storage Class

11 - Combustible Solids

wgk

nwg

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
13304MY
05018TI

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Simon Duttwyler et al.
Science (New York, N.Y.), 339(6120), 678-682 (2013-02-09)
Piperidines are prevalent in natural products and pharmaceutical agents and are important synthetic targets for drug discovery and development. We report on a methodology that provides highly substituted piperidine derivatives with regiochemistry selectively tunable by varying the strength of acid
P Andrew Evans et al.
Organic letters, 15(8), 1798-1801 (2013-04-02)
A concise and highly convergent three-step total synthesis of the lactarane natural product, pyrovellerolactone, is described. The key step involves a regio- and diastereoselective rhodium-catalyzed [(3 + 2) + 2] carbocyclization of an alkenylidenecyclopropane with a 4-hydroxybut-2-ynoate followed by an
Xian-Ying Shi et al.
Organic letters, 15(7), 1476-1479 (2013-03-09)
A novel rhodium(III)-catalyzed direct functionalization of the ortho-C-H bond of aromatic ketone derivatives and an intramolecular cyclization sequence produced indene derivatives in moderate to good yields. This cascade cyclization involves a conjugate addition of α,β-unsaturated ketone and subsequent aldol condensation.
Juliane Keilitz et al.
Organic letters, 15(5), 1148-1151 (2013-02-21)
A new enantioselective rhodium-catalyzed domino reaction is described that gives access to fused heterocycles by desymmetrization of alkyne-tethered cyclohexadienones. Two new C-C bonds and two stereocenters are formed in one step with good enantioselectivity. In contrast to prior reports, it
Gavin Chit Tsui et al.
Organic letters, 15(5), 1064-1067 (2013-02-12)
A method for synthesizing chiral oxazolidinone scaffolds from readily available oxabicyclic alkenes is described. The reaction utilizes a domino sequence of Rh(I)-catalyzed asymmetric ring-opening (ARO) with sodium cyanate as a novel nucleophile followed by intramolecular cyclization to generate oxazolidinone products
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