357405
Zirconium(IV) chloride
≥99.9% trace metals basis
Synonym(s):
Tetrachlorozirconium, Zirconium tetrachloride
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About This Item
vapor pressure
1 mmHg ( 190 °C)
Quality Level
Assay
≥99.9% trace metals basis
form
powder
reaction suitability
core: zirconium
reagent type: catalyst
greener alternative product characteristics
Catalysis
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impurities
≤1000.0 ppm Trace Metal Analysis
transition temp
sublimation point 331 °C
density
2.8 g/mL at 25 °C (lit.)
greener alternative category
SMILES string
Cl[Zr](Cl)(Cl)Cl
InChI
1S/4ClH.Zr/h4*1H;/q;;;;+4/p-4
InChI key
DUNKXUFBGCUVQW-UHFFFAOYSA-J
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Application
- electrophilic addition reaction of indole with aldehydes/ketones to form bis(indolyl)methanes. electrophilic amination of activated arenes,
- transthioacetylization of acetals,
- deoxygenation of heterocyclic-N-oxides,
- reduction of nitro compounds,
- conversion of carbonyl compounds to 1,3-oxathiolanes,
- Biginelli reaction for the synthesis of 3,4-dihydropyrimidin-2(1H)-ones,
- direct amide coupling of non activated carboxylic acids and amines,
- synthesis of quinoxalines and pyrido[2,3-b]pyrazines,
- deprotection of t-butyldimethylsilyl (TBDMS) ethers.
Features and Benefits
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Met. Corr. 1 - Skin Corr. 1B
Supplementary Hazards
Storage Class Code
8A - Combustible corrosive hazardous materials
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
Regulatory Information
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