358819
二甲基三甲硅基膦酸酯
95%
别名:
Trimethylsilyl dimethyl phosphite
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关于此项目
线性分子式:
(CH3)3SiOP(OCH3)2
化学文摘社编号:
分子量:
182.23
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
252-908-3
Beilstein/REAXYS Number:
1849308
MDL number:
Assay:
95%
Form:
liquid
Quality Segment
assay
95%
form
liquid
refractive index
n20/D 1.410 (lit.)
bp
36-37 °C/11 mmHg (lit.)
density
0.954 g/mL at 25 °C (lit.)
storage temp.
2-8°C
SMILES string
COP(OC)O[Si](C)(C)C
InChI
1S/C5H15O3PSi/c1-6-9(7-2)8-10(3,4)5/h1-5H3
InChI key
HWMXPTIFAGBDIK-UHFFFAOYSA-N
Application
Dimethyl trimethylsilyl phosphite may be used in the preparation of:
- protected phosphoamino acid, Fmoc-Abu(PO3Me2)-OH, used in Fmoc/solid-phase peptide synthesis
- phosphoenolpyruvate (PEP) via trimethylsilylation, bromination and Perkow reaction
- sialyl phosphonate
- sulfonamide phosphonates
signalword
Danger
hcodes
Hazard Classifications
Flam. Liq. 3 - Skin Corr. 1B
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
89.6 °F - closed cup
flash_point_c
32 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter