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Merck
CN

360163

Sigma-Aldrich

trans-Dibromobis(triphenylphosphine)palladium(II)

95%

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About This Item

Linear Formula:
[(C6H5)3P]2PdBr2
CAS Number:
Molecular Weight:
790.80
MDL number:
UNSPSC Code:
12352300
PubChem Substance ID:
NACRES:
NA.22
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Assay

95%

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

SMILES string

Br[Pd]Br.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6

InChI

1S/2C18H15P.2BrH.Pd/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;2*1H;/q;;;;+2/p-2

InChI key

MCSDDEAMPOYJJI-UHFFFAOYSA-L

Application

Catalyst for:
  • Equilibrium palladation of alkanes and arenes and functionalization of hydrocarbons

Reactant for:
  • Homocoupling reactions induced by P-C reductive elimination
  • Preparation of palladium imidazolylidene complexes via Suzuki coupling reactions

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Information

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Yamagata Daigaku Kiyo, Kogaku, 20, 141-141 (1988)
Chem. Abstr., 111, 80291w-80291w (1989)

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