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361267

cis-1,2-Cyclohexanediol

Name: <I>cis</I>-1,2-Cyclohexanediol
Brand: ALDRICH

99%

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About This Item

Linear Formula:

C₆H₁₀(OH)₂

CAS Number:

1792-81-0

Molecular Weight:

116.16

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24862178

MDL number:

MFCD00064944

Beilstein/REAXYS Number:

1340578

Assay:

99%

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Properties

Quality Level

200

assay

99%

mp

97-101 °C (lit.)

functional group

hydroxyl

SMILES string

O[C@@H]1CCCC[C@@H]1O

InChI

1S/C6H12O2/c7-5-3-1-2-4-6(5)8/h5-8H,1-4H2/t5-,6+

InChI key

PFURGBBHAOXLIO-OLQVQODUSA-N

Description

General description

Core-shell-like silica nickel species nanoparticle catalyzed dehydrogenation of 1,2-cyclohexanediol to catechol is reported. Crystal structure of a Cr(V) complex with cis-1,2-cyclohexanediol is reported. Enzymatic oxidation of cis-1,2-cyclohexanediol by Gluconobacter oxydans (ATCC 621) is reported.

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

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Isolation, characterization, and nuclease activity of biologically relevant chromium(V) complexes with monosaccharides and model diols. Likely intermediates in chromium-induced cancers.

Ruben Bartholomäus et al.

Inorganic chemistry, 52(8), 4282-4292 (2013-03-28)

The stabilization of Cr(V) by biological 1,2-diolato ligands, including carbohydrates, glycoproteins, and sialic acid derivatives, is likely to play a crucial role in the genotoxicity of Cr(VI) and has also been implicated in the antidiabetic effect of Cr(III). Previously, such

Oxidation of trans-and cis-1, 2-cyclohexanediol by Gluconobacter oxydans.

Adlercreutz P.

Applied Microbiology and Biotechnology, 30(3), 257-263 (1989)

A simple and convenient approach for preparing core-shell-like silica@nickel species nanoparticles: highly efficient and stable catalyst for the dehydrogenation of 1,2-cyclohexanediol to catechol.

Bao-Hui Chen et al.

Dalton transactions (Cambridge, England : 2003), 44(3), 1023-1038 (2014-11-20)

A simple and convenient approach denoted as gel-deposition-precipitation (G-D-P) for the preparation of core-shell-like silica@nickel species nanoparticles was studied systematically. Core-shell-like silica@nickel species nanoparticles consisted of a Si-rich core and a Ni-rich shell. The G-D-P process included two steps: one

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Global Trade Item Number

SKU	GTIN
361267-1G	04061831824100