362174
(Bicyclo[2.2.1]hepta-2,5-diene)dichloropalladium(II)
98%
Synonym(s):
Dichloro (norbornadiene)palladium(II), NSC 176915, PdCl2(nbd)
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About This Item
InChI key
BNCRZJHZZCMDNP-UHFFFAOYSA-L
InChI
1S/C7H8.2ClH.Pd/c1-2-7-4-3-6(1)5-7;;;/h1-4,6-7H,5H2;2*1H;/q;;;+2/p-2
SMILES string
Cl[Pd]Cl.[CH]1[CH]C2[CH][CH]C1C2
assay
98%
reaction suitability
core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
mp
260 °C (dec.) (lit.)
Application
- Aerobic kinetic resolution of secondary alcohols
- Kinetic oxidative resolution of 1-phenyl ethanol
- Oxidative kinetic resolution-Claisen rearrangement sequence
- Aerobic oxidation of secondary alcohols
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
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