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Merck
CN

362212

Iododioxobis(triphenylphosphine)rhenium(V)

98%

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About This Item

Linear Formula:
[(C6H5)3P]2ReO2I
CAS Number:
Molecular Weight:
869.68
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352300
MDL number:
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InChI

1S/2C18H15P.HI.2O.Re/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;;/h2*1-15H;1H;;;/q;;;;;+1/p-1

SMILES string

I[Re](=O)=O.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6

InChI key

PMWGPGWRMJAPNT-UHFFFAOYSA-M

assay

98%

form

solid

reaction suitability

core: rhenium, reagent type: catalyst

mp

195-197 °C (lit.)

Application

Catalyst for:
  • Chemoselective direct reductive amination reactions
  • Selective hydrogenation reactions
  • Living radical polymerization reactions

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)


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