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About This Item
Linear Formula:
CH3ON(CH3)COCH2P(O)(OC2H5)2
CAS Number:
Molecular Weight:
239.21
Beilstein:
1875865
MDL number:
UNSPSC Code:
12352108
PubChem Substance ID:
NACRES:
NA.22
Assay
96%
form
liquid
reaction suitability
reaction type: C-C Bond Formation
refractive index
n20/D 1.455 (lit.)
bp
90 °C/17 mmHg (lit.)
density
1.163 g/mL at 25 °C (lit.)
functional group
amine
phosphonate
SMILES string
CCOP(=O)(CC(=O)N(C)OC)OCC
InChI
1S/C8H18NO5P/c1-5-13-15(11,14-6-2)7-8(10)9(3)12-4/h5-7H2,1-4H3
InChI key
WYLRYBDGIILFIR-UHFFFAOYSA-N
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Application
Reactant for:
- Preparation of ring-expanded bryostatin analogs as antitumor agents
- Asymmertic synthesis of pinnatoxins A and G via diastereoselective Ireland-Claisen rearrangement, ring closing metathesis, and cyclization
- Rh2(II)-catalyzed nitro-group migration reactions
- Stereoselective synthesis of cyclohexanones via phase transfer catalyzed double addition reactions
- Stereoselective synthesis of (+)-polyrhacitide A via aldol reaction, Horner-Wardsworth-Emmons reaction, Evans acetal intramolecular oxa-Michael reaction and diastereoselective syn reduction reaction as the key steps
- Preparation of substituted furans via olefin cross-metathesis
Wittig carbonylating reagent.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
10 - Combustible liquids
WGK
WGK 3
Flash Point(F)
230.0 °F - closed cup
Flash Point(C)
110 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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