365203
Lithium p-toluenesulfinate
98%
Synonym(s):
p-Toluenesulfinic acid lithium salt
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About This Item
Linear Formula:
CH3C6H4SO2Li
CAS Number:
Molecular Weight:
162.14
EC Number:
240-867-4
UNSPSC Code:
12352100
PubChem Substance ID:
Beilstein/REAXYS Number:
4163977
MDL number:
Assay:
98%
InChI key
MSUZXYWQEDRGFN-UHFFFAOYSA-M
InChI
1S/C7H8O2S.Li/c1-6-2-4-7(5-3-6)10(8)9;/h2-5H,1H3,(H,8,9);/q;+1/p-1
SMILES string
[Li+].Cc1ccc(cc1)S([O-])=O
assay
98%
impurities
≤2% Li2CO3
Application
Lithium p-toluenesulfinate may be used in the preparation of 2-oxo-1,3-diphenyl-1,2-dihydroquinoline-4-carbonitrile. It may be used in the preparation of highly fluorescent compound, 3-amino-6-methoxy-4-p-tolylsulfonylquinolone.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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4-Cyano-6, 7-dimethoxycarbostyrils with Solvent-and pH-Independent High Fluorescence Quantum Yields and Emission Maxima.
Ahvale AB, et al.
European Journal of Organic Chemistry, 3, 563-571 (2008)
Month 2013 6-Methoxy-2-oxo-1, 2-dihydroquinoline-3, 4-dicarbonitriles, A Red Compound Class with Solvent and pH Independent Green Fluorescence Maxima.
Enoua GC, et al.
Journal of Heterocyclic Chemistry, 51, 492-501 (2014)
Xiaoxiang Zhang et al.
The Journal of organic chemistry, 75(18), 6290-6293 (2010-08-28)
A general and efficient method to prepare 2,4-di- and trisubstituted thiazoles via p-TsOH·H(2)O-catalyzed cyclization of trisubstituted propargylic alcohols with thioamides is described. The reaction was accomplished in moderate to excellent product yields under mild conditions that did not require the
K Eulitz et al.
Lipids, 34(8), 873-877 (1999-10-21)
Conjugated linoleic acid (CLA) mixtures were isomerized with p-toluenesulfinic acid or I2 catalyst. The resultant mixtures of the eight cis/trans geometric isomers of 8,10-, 9,11-, 10,12-, and 11,13-octadecadienoic (18:2) acid methyl esters were separated by silver ion-high-performance liquid chromatography (Ag+-HPLC)
T Lyubimova et al.
Electrophoresis, 14(1-2), 40-50 (1993-01-01)
Photopolymerization of polyacrylamide gels in the presence of methylene blue (100 microM) and a redox couple (1 mM sodium toluenesulfinate, a reducer, and 50 microM diphenyliodonium chloride, an oxidizer) has been investigated. The gel point, i.e. the time needed for
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