366498
2-(Methyldiphenylsilyl)ethanol
99%
Synonym(s):
(2-Hydroxyethyl)diphenylmethylsilane, 2-(Diphenylmethylsilyl)ethanol
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About This Item
Linear Formula:
CH3Si(C6H5)2CH2CH2OH
CAS Number:
Molecular Weight:
242.39
Beilstein:
4428743
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
Assay
99%
form
liquid
refractive index
n20/D 1.580 (lit.)
bp
152 °C/0.2 mmHg (lit.)
density
1.063 g/mL at 25 °C (lit.)
functional group
hydroxyl
SMILES string
C[Si](CCO)(c1ccccc1)c2ccccc2
InChI
1S/C15H18OSi/c1-17(13-12-16,14-8-4-2-5-9-14)15-10-6-3-7-11-15/h2-11,16H,12-13H2,1H3
InChI key
RYVPOJDQPLVTLT-UHFFFAOYSA-N
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Application
2-(Methyldiphenylsilyl)ethanol (2-(Diphenylmethylsilyl)ethanol) may be used in the preparation of 2-diphenylmethylsilylethyldithiophosphorodichloridate.
Storage Class Code
10 - Combustible liquids
WGK
WGK 3
Flash Point(F)
230.0 °F - closed cup
Flash Point(C)
110 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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D C Capaldi et al.
Nucleic acids research, 28(9), E40-E40 (2000-04-11)
A triester method for the synthesis of deoxynucleoside phosphorodithioate dimers is described. The phosphorodithioate linkage is introduced using a new dithiophosphorylating reagent DPSE-SP(S)Cl(2)where DPSE = 2-diphenylmethylsilylethyl. This group is removed quickly using tetra-butylammonium fluoride leading to the quantitative formation of
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