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About This Item
Linear Formula:
Cu(BF4)2 · xH2O
CAS Number:
Molecular Weight:
237.16 (anhydrous basis)
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23
Form:
solid
form
solid
composition
Cu(II), 19-22%
reaction suitability
core: copper
concentration
≤25.8% Cu (EDTA titration)
SMILES string
O.[Cu++].F[B-](F)(F)F.F[B-](F)(F)F
InChI
1S/2BF4.Cu.H2O/c2*2-1(3,4)5;;/h;;;1H2/q2*-1;+2;
InChI key
JYLPBVRGTDBGBM-UHFFFAOYSA-N
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Application
Copper(II) tetrafluoroborate hydrate may be used as catalyst for chemoselective N-tert-butoxycarbonylation of amines with di-tert-butyl dicarbonate.The product is a starting material for homometallic, trinuclear heteroscorpionate complexes applied in studies of electronic and magnetic properties.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B
Storage Class Code
8A - Combustible corrosive hazardous materials
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Copper(II) tetrafluoroborate as a novel and highly efficient catalyst for N-tert-butoxycarbonylation of amines under solvent-free conditions at room temperature
Chankeshwara SV, et al.
Tetrahedron Letters, 47(7), 1087-1091 (2006)
Jin Shen et al.
Nature communications, 11(1), 6259-6259 (2020-12-09)
Three-dimensional metal-organic frameworks (MOFs) are cutting-edge materials in the adsorptive removal of trace gases due to the availability of abundant pores with specific chemistry. However, the development of ideal adsorbents combining high adsorption capacity with high selectivity and stability remains
Timothy C. Higgs et al.
Inorganic chemistry, 37(9), 2263-2272 (2001-10-24)
The mixed functionality pyrazole/phenol ligand (2-hydroxyphenyl)bis(pyrazolyl)methane, L1OH, has been used to prepare a series of linear trimetallic systems with the general structural motif [M(3)(L1O)(4)](2+), where M = Mn(2+), Co(2+), Ni(2+), Cu(2+), and Zn(2+). Each of these complexes has been structurally
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