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Merck
CN

366587

Copper(II) tetrafluoroborate hydrate

Synonym(s):

Copper ditetrafluoroborate hydrate, Cupric tetrafluoroborate hydrate

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About This Item

Linear Formula:
Cu(BF4)2 · xH2O
CAS Number:
207121-39-9
Molecular Weight:
237.16 (anhydrous basis)
NACRES:
NA.23
PubChem Substance ID:
24862673
UNSPSC Code:
12352302
MDL number:
MFCD00150223
Form:
solid

Key Documents

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InChI

1S/2BF4.Cu.H2O/c2*2-1(3,4)5;;/h;;;1H2/q2*-1;+2;

SMILES string

O.[Cu++].F[B-](F)(F)F.F[B-](F)(F)F

InChI key

JYLPBVRGTDBGBM-UHFFFAOYSA-N

form

solid

composition

Cu(II), 19-22%

reaction suitability

core: copper

concentration

≤25.8% Cu (EDTA titration)

Quality Level

100

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Application

Copper(II) tetrafluoroborate hydrate may be used as catalyst for chemoselective N-tert-butoxycarbonylation of amines with di-tert-butyl dicarbonate.The product is a starting material for homometallic, trinuclear heteroscorpionate complexes applied in studies of electronic and magnetic properties.

pictograms

CorrosionExclamation mark
GHS05,GHS07

signalword

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificates of Analysis (COA)

Lot/Batch Number
0000300626
MKCW0788
0000300626
MKCT0286
MKCV3994

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Copper(II) tetrafluoroborate as a novel and highly efficient catalyst for N-tert-butoxycarbonylation of amines under solvent-free conditions at room temperature
Chankeshwara SV, et al.
Tetrahedron Letters, 47(7), 1087-1091 (2006)
Jin Shen et al.
Nature communications, 11(1), 6259-6259 (2020-12-09)
Three-dimensional metal-organic frameworks (MOFs) are cutting-edge materials in the adsorptive removal of trace gases due to the availability of abundant pores with specific chemistry. However, the development of ideal adsorbents combining high adsorption capacity with high selectivity and stability remains
Timothy C. Higgs et al.
Inorganic chemistry, 37(9), 2263-2272 (2001-10-24)
The mixed functionality pyrazole/phenol ligand (2-hydroxyphenyl)bis(pyrazolyl)methane, L1OH, has been used to prepare a series of linear trimetallic systems with the general structural motif [M(3)(L1O)(4)](2+), where M = Mn(2+), Co(2+), Ni(2+), Cu(2+), and Zn(2+). Each of these complexes has been structurally

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