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368873

9-Bromo-9-phenylfluorene

97%

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About This Item

Empirical Formula (Hill Notation):
C19H13Br
CAS Number:
55135-66-5
Molecular Weight:
321.21
NACRES:
NA.22
PubChem Substance ID:
24862938
UNSPSC Code:
12352100
MDL number:
MFCD00075522
Assay:
97%
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assay

97%

mp

99-101 °C (lit.)

functional group

bromo, phenyl

SMILES string

BrC2(c1ccccc1)c3ccccc3-c4ccccc24

InChI

1S/C19H13Br/c20-19(14-8-2-1-3-9-14)17-12-6-4-10-15(17)16-11-5-7-13-18(16)19/h1-13H

InChI key

HYQXNCDBSALQLB-UHFFFAOYSA-N

General description

Solvolysis of 9-bromo-9- phenylfluorene has been reported to proceed via limiting SN1 mechanism.

Application

9-Bromo-9-phenylfluorene may be used in the preparation of:
  • N-(9-(9-phenylfluorenyl))-L-alaninal
  • N-(9-phenylfluoren-9-yl)-L-serine
  • 1-hydroxypyrazoles priotected at the oxygen atom

pictograms

Corrosion
GHS05

signalword

Danger

hcodes

H314

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
0000083805
0000071401
03907CJ
07223LD
06412KD

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Configurational stability of N-protected. alpha.-amino aldehydes.
Lubell WD and Rapoport H.
Journal of the American Chemical Society, 109(1), 236-239 (1987)
Synthesis of 5-substituted 1-hydroxypyrazoles through directed lithiation of 1-(benzyloxy) pyrazole.
Vedso P and Begtrup M.
The Journal of Organic Chemistry, 60(16), 4995-4998 (1995)
Solvent and Substituent Effects in the Solvolysis of 9-Aryl-9-bromofluorenes.
Liu K-T and Lin Y-S.
J. Chin. Chem. Soc., 47(1), 71-76 (2000)
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Global Trade Item Number

SKUGTIN
368873-5G04061832687575