369055
2-Bromo-4-fluoroaniline
97%
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About This Item
Linear Formula:
BrC6H3(F)NH2
CAS Number:
Molecular Weight:
190.01
UNSPSC Code:
12352100
PubChem Substance ID:
MDL number:
Product Name
2-Bromo-4-fluoroaniline, 97%
InChI
1S/C6H5BrFN/c7-5-3-4(8)1-2-6(5)9/h1-3H,9H2
SMILES string
Nc1ccc(F)cc1Br
InChI key
YLMFXCIATJJKQL-UHFFFAOYSA-N
assay
97%
form
solid
refractive index
n20/D 1.583 (lit.)
bp
221 °C (lit.)
density
1.67 g/mL at 25 °C (lit.)
functional group
bromo
fluoro
General description
2-Bromo-4-fluoroaniline is an aryl fluorinated building block.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
219.2 °F - closed cup
flash_point_c
104 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Regulatory Information
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Fatma K Abdel-Wadood et al.
Archiv der Pharmazie, 347(2), 142-152 (2014-01-01)
2-Bromo-4-fluoroaniline (1) was condensed with ethyl 2-cyano-3-ethoxyacrylate (2) in ethanol to afford 3, which upon refluxing in paraffin oil at 250°C gave 8-bromo-3-cyano-6-fluoroquinoline-4(1H)-one (4). Then, compound 4 was taken as a versatile building block that allows the synthesis of thieno[3,2-c]quinoline
Synthesis of fluorescent tetracyclic lactams by a ?one pot? three steps palladium-catalyzed borylation, Suzuki coupling (BSC) and lactamization: DNA and polynucleotides binding studies.
Queiroz M-JRP, et al.
Journal of Photochemistry and Photobiology A: Chemistry, 190(1), 45-52 (2007)
An efficient synthesis of enantiomerically pure aromatic-fused N-containing heterocycles from common chiral aziridines.
Chan Kim J, et al.
Tetrahedron, 66(40), 8108-8114 (2010)
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