369330
N-tert-Butyltrimethylsilylamine
98%
Synonym(s):
N-(Trimethylsilyl)-tert-butylamine
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About This Item
Linear Formula:
(CH3)3SiNHC(CH3)3
CAS Number:
Molecular Weight:
145.32
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
1734528
Assay:
98%
Form:
liquid
InChI
1S/C7H19NSi/c1-7(2,3)8-9(4,5)6/h8H,1-6H3
SMILES string
CC(C)(C)N[Si](C)(C)C
InChI key
GVHIREZHTRULPT-UHFFFAOYSA-N
assay
98%
form
liquid
refractive index
n20/D 1.406 (lit.)
Quality Level
density
0.762 g/mL at 25 °C (lit.)
functional group
amine
Related Categories
General description
N-tert-Butyltrimethylsilylamine (Me3SiNH-t-Bu) reacts with [Cp*Rh(H2O)3](OTf)2 in acetone to yield a hydroxyl-capped half-cubane [Cp*3Rh3(μ-OH)3(μ3-OH)](OTf)3(t-BuNH3).
Application
N-tert-Butyltrimethylsilylamine may be used in the preparation of selenium and tellurium chalcogenides and the facile synthesis of N-alkylaminomethylphosphonates.
signalword
Danger
hcodes
Hazard Classifications
Flam. Liq. 3 - Skin Corr. 1B
Storage Class
3 - Flammable liquids
wgk
WGK 3
flash_point_f
78.8 °F - closed cup
flash_point_c
26 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Regulatory Information
危险化学品
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Won Seok Han et al.
Dalton transactions (Cambridge, England : 2003), (20)(20), 3360-3364 (2004-10-16)
Treatment of [Cp*Rh(H(2)O)(3)](OTf)(2) (1) with Me(3)SiNH-t-Bu in acetone gave a hydroxyl-capped half-cubane [Cp*(3)Rh(3)(mu-OH)(3)(mu(3)-OH)](OTf)(3)(t-BuNH(3)) (2). Slow diffusion of Me(3)SiN(3) in diethyl ether into compound in acetone produced an azido-capped half-cubane [Cp*(3)Rh(3)(mu-N(3))(3)(mu(3)-N(3))](OTf)(2) (3). On the other hand, treating 1 with Me(3)SiN(3) in
J. Solid State Inorg. Chem., 29, 759-759 (1992)
Synthetic Communications, 21, 201-201 (1991)
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