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Merck
CN

371440

(1-tert-Butylvinyloxy)trimethylsilane

98%

Synonym(s):

(2,2-Dimethyl-1-methylenepropoxy)trimethylsilane, 3,3-Dimethyl-2-trimethylsiloxy-1-butene, Pinacolone enol trimethylsilyl ether

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About This Item

Linear Formula:
(CH3)3CC(=CH2)OSi(CH3)3
CAS Number:
17510-46-2
Molecular Weight:
172.34
Beilstein:
2204704
MDL number:
MFCD00075567
UNSPSC Code:
12352100
PubChem Substance ID:
24863107
NACRES:
NA.22

Key Documents

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Assay

98%

form

liquid

refractive index

n20/D 1.409 (lit.)

bp

140-142 °C (lit.)

density

0.798 g/mL at 25 °C (lit.)

SMILES string

CC(C)(C)C(=C)O[Si](C)(C)C

InChI

1S/C9H20OSi/c1-8(9(2,3)4)10-11(5,6)7/h1H2,2-7H3

InChI key

PEHJULPJEVIIFJ-UHFFFAOYSA-N

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General description

(1-tert-Butylvinyloxy)trimethylsilane is a silyl enol. It belongs to organosilicone class of compounds. Enthalpy of vaporization of (1-tert-Butylvinyloxy)trimethylsilane at boiling point has been reported.

Application

(1-tert-Butylvinyloxy)trimethylsilane ((2,2-Dimethyl-1-methylenepropoxy)trimethylsilane) may be used in the synthesis of cis-3,3-dimethyl-1-(6-phenethyl-3,6-dihydro-2H-pyran-2-yl)butan-2-one.
(1-tert-Butylvinyloxy)trimethylsilane may be used in the preparation of 1-(4-bromophenyl)-4,4-dimethylpentan-3-one.

Pictograms

FlameExclamation mark
GHS02,GHS07

Signal Word

Warning

Hazard Statements

H226,H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

75.2 °F - closed cup

Flash Point(C)

24 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

危险化学品
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Certificates of Analysis (COA)

Lot/Batch Number
MKCH3796
MKBS7861V
MKBB2546
16424KH
02720LE

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Salvatore Ferla et al.
Journal of medicinal chemistry, 57(18), 7702-7715 (2014-08-26)
The synthesis of imidazole styrylbenzamide, tert-butyl styrylimidazole, and tert-butyl styrylsulfonate derivatives is described. Evaluation of binding affinity and inhibitory activity against CYP24A1 identified the imidazole styrylbenzamides as potent inhibitors of CYP24A1, having selectivity with respect to CYP27B1 comparable with or
Yaws CL.
Thermophysical Properties of Chemicals and Hydrocarbons, 574-574 (2014)
Robert J Hinkle et al.
Tetrahedron, 65(34), 6834-6839 (2010-02-18)
The rapid synthesis of cis-2,6-disubstituted dihydropyrans is achieved in a three-component, one-pot cascade reaction. BiBr(3)-ediated addition of ketene silyl acetals or silyl enol ethers to beta,gamma-unsaturated cis-4-trimethylsilyl-3-butenal provides a Mukaiyama aldol adduct containing a vinylsilane moiety tethered to a silyl

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