371963
Hexafluoropropene, trimer
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About This Item
Linear Formula:
[CF3C(F)=CF2]3
CAS Number:
Molecular Weight:
450.07
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
form
liquid
Quality Level
bp
110-115 °C (lit.)
density
1.83 g/mL at 25 °C (lit.)
functional group
fluoro
SMILES string
FC(F)=C(F)C(F)(F)F.FC(F)=C(F)C(F)(F)F.FC(F)=C(F)C(F)(F)F
InChI
1S/3C3F6/c3*4-1(2(5)6)3(7,8)9
InChI key
VJRSWIKVCUMTFK-UHFFFAOYSA-N
General description
Spectra of three isomeric trimers of hexafluoropropene have been investigated. It reacts with primary amines, via indirect substitution of fluorine atoms, to form the corresponding enamines and enimines.
Application
Hexafluoropropene, trimer may be used in the preparation of photochromic spiroindolinonaphthoxazine derivative. It may be used in the preparation of 2-trifluoromethyl-3-heptadifluoroisopropyl-2-perfluoropentene-4-(N′,N′-dimethylamino propyl) imino(I).
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point(F)
75.2 °F - closed cup
Flash Point(C)
24 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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Interaction of hexafluoropropene trimers with ammonia and primary amines.
Del'tsova DP, et al.
Journal of Fluorine Chemistry, 79(1), 97-102 (1996)
Synthesis and NMR study of 9'-substituted spiroindolinonaphthoxazine derivatives.
Kakishita T, et al.
Journal of Heterocyclic Chemistry, 29(7), 1709-1715 (1992)
Non-bond F? F nuclear spin couplings II. Hexafluoropropene trimers.
Cavagna F and Schumann C.
Journal of Magnetic Resonance, 22(2), 333-334 (1969)
Synthesis of Fluoro-tertiary and Quaternary Ammonium Cationic Surfactants [J].
Jingfeng LZ, et al.
Dyestuffs and Coloration / Ran Liao Yu Ran Shai, 1, 009-009 (2006)
Jost Leemhuis et al.
The Journal of pharmacology and experimental therapeutics, 300(3), 1000-1007 (2002-02-28)
The small GTPase RhoA can retract cell extensions by acting on two Rho kinases (ROCKs). Activated protein kinase A (PKA) inhibits RhoA and induces extensions. The isoquinoline H89 inhibits PKA and thus should prevent the inactivation of RhoA. In kinase
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