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Merck
CN

372439

Perfluoro(methyldecalin), mixture of isomers

technical grade, 80%

Synonym(s):

Heptadecafluorodecahydro(trifluoromethyl)naphthalene

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About This Item

Empirical Formula (Hill Notation):
C11F20
CAS Number:
51294-16-7
Molecular Weight:
512.09
UNSPSC Code:
12352100
PubChem Substance ID:
24863035
NACRES:
NA.22

Key Documents

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grade

technical grade

Quality Level

100

Assay

80%

form

liquid

refractive index

n20/D 1.317 (lit.)

bp

137-160 °C (lit.)

mp

−40 °C (lit.)

density

1.95 g/mL at 25 °C (lit.)

SMILES string

FC(F)(F)C1(F)C(F)(F)C(F)(F)C2(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C2(F)C1(F)F.FC(F)(F)C3(F)C(F)(F)C(F)(F)C(F)(F)C4(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C34F

InChI

1S/C11F20/c12-1-2(13,6(19,20)10(27,28)9(25,26)4(1,15)16)5(17,18)8(23,24)7(21,22)3(1,14)11(29,30)31

InChI key

LWRNQOBXRHWPGE-UHFFFAOYSA-N

Related Categories

General description

Perfluoro(methyldecalin) is a fluorinated solvent.

Application

Perfluoro(methyldecalin is suitable reagent used to investigate the reactions of iodide anions and anions derived from glow discharge ionization of perfluoro(methyldecalin) with positive ions derived from poly(ethylene glycol). It is suitable reagent used for the oxidation of alcohols with the ruthenium porphyrin at higher temperatures (140ºC) and elevated oxygen pressures (50psi). Perfluoro(methyldecalin (Perfluoro-1-Methyldecalin) may be used in the preparation of undecafluoro-6-trifluoromethyltetralin via defluorination.

Other Notes

Contains perfluorodecalin

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

235.0 °F - closed cup

Flash Point(C)

112.80 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
MKCR6988
MKCR2138
MKCP2231
MKCL3965
MKCK8963

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M K Bakulin et al.
Prikladnaia biokhimiia i mikrobiologiia, 43(4), 443-449 (2007-10-13)
The addition of perfluorocarbons (perfluorodecalin, carbogal, and perfluoromethyldecalin) to nitrogen-free liquid media during the submerged cultivation of bacteria of the genus Azotobacter was followed by (1) increases in biomass accumulation and nitrogenase activity and (2) fixation of molecular nitrogen. Addition
37. Polycyclic fluoroaromatic compounds. Part II. Perfluoromethylnaphthalenes and derived compounds.
Gething B, et al.
Journal of the Chemical Society, 190-193 (1962)
D J McIver et al.
Biochimica et biophysica acta, 751(1), 74-80 (1983-03-22)
An effective substitute for pulmonary surfactant must be able to reduce water-vapour surface tensions to under 1 mN/m and it must spread rapidly and spontaneously at the air interface from the aqueous phase. Pure dipalmitoylphosphatidylcholine meets the former requirement, but
Vasily N Korotchenko et al.
Organic & biomolecular chemistry, 6(11), 1961-1965 (2008-05-16)
Carbonylruthenium tetrakis(pentafluorophenyl)porphyrin Ru(TPFPP)(CO) was utilized for the aerobic oxidation of alcohols. The in situ activation of the catalyst with mCPBA provided a species capable of catalyzing the oxidation of alcohols with molecular oxygen. The choice of solvent and additive was
M K Bakulin et al.
Mikrobiologiia, 75(3), 371-376 (2006-07-29)
The isolates of pseudomonads (56) and of Plesiomonas shigelloides (7) exhibiting ice-forming activity were isolated from plant leaves and rhizosphere. The theoretical possibility of the application of perfluorocarbons (PFC) with a gas-transporting function (perfluorodecalin, carbogal, and perfluoromethyldecalin) for the cultivation
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