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Merck
CN

375187

Trimethyltin chloride solution

1.0 M in hexanes

Synonym(s):

Chlorotrimethylstannane, Chlorotrimethyltin, Trimethylchlorostannane, Trimethylchlorotin, Trimethylstannyl chloride, Trimethyltin chloride

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About This Item

Linear Formula:
(CH3)3SnCl
CAS Number:
1066-45-1
Molecular Weight:
199.27
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
24863370
MDL number:
MFCD00000520
Beilstein/REAXYS Number:
3535111

Key Documents

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Product Name

Trimethyltin chloride solution, 1.0 M in hexanes

InChI

1S/3CH3.ClH.Sn/h3*1H3;1H;/q;;;;+1/p-1

SMILES string

C[Sn](C)(C)Cl

InChI key

KWTSZCJMWHGPOS-UHFFFAOYSA-M

form

liquid

concentration

1.0 M in hexanes

density

0.797 g/mL at 25 °C

Quality Level

100

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Packaging

The 25 mL Sure/Seal™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.

Legal Information

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

Application

Trimethyltin chloride solution (1.0 M in hexanes) can be used as a reagent in the synthesis of conjugated polymers based on isoindigo as acceptor and syn- or anti-benzo[1,2-b:5,4-b′]difuran (BDF) as a donor by Stille cross-coupling reaction. It can further be used for the investigation of optical, electrochemical and photovoltaic properties.

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Danger

Hazard Classifications

Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Asp. Tox. 1 - Flam. Liq. 2 - Repr. 2 - Skin Irrit. 2 - STOT RE 1 Inhalation - STOT SE 3

target_organs

Central nervous system, Nervous system

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

-9.4 °F - closed cup

flash_point_c

-23 °C - closed cup

Regulatory Information

危险化学品
非剧毒-急性毒性1
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Certificates of Analysis (COA)

Lot/Batch Number
MKCS2486
MKCS2490
MKCP9053
MKCN7621
SHBJ8521

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Synthesis and photovoltaic properties of new conjugated polymers based on syn-and anti-benzodifuran
Hu C, et al.
Polym. Chem., 3(10), 2949-2955 (2012)
Ana-Maria Florea et al.
Cell calcium, 37(3), 251-258 (2005-01-27)
Humans are exposed to organotins, like trimethyltin (TMT) chloride via air, water and food, and intoxication might result in severe health complications. Toxic effects of organotin compounds are well documented, but possible mechanisms remain unclear and only little information is
Koichi Kawada et al.
Journal of neuroscience research, 86(7), 1635-1646 (2008-01-10)
Our earlier study demonstrated that in vivo acute treatment with trimethyltin chloride (TMT) produces severe neuronal damage in the dentate gyrus and cognition impairment in mice. In the present study, we assessed whether TMT was capable of causing neuronal degeneration
Nguyen Quynh Huong et al.
Biological & pharmaceutical bulletin, 34(12), 1856-1863 (2011-12-02)
The organotin trimethyltin (TMT) is well known to cause neuronal degeneration in the hippocampal dentate gyrus of mice. The first purpose of the present study was to examine whether the cyclooxygenase (COX) inhibitor indomethacin could ameliorate neuronal degeneration in the
Jiali Cai et al.
Chemical research in toxicology, 22(9), 1582-1587 (2009-08-07)
In evaluating the cytotoxic effects and the mechanisms of the apoptotic and necrotic actions of trimethyltin chloride (TMT) on human hepatoma G2 (HepG2) cells, the present study focused on the involvement of antiproliferation, DNA damage, cell death, apoptosis-related proteins, and
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