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379875

Sigma-Aldrich

[Pd(OAc)2]3

99.98% trace metals basis

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Synonym(s):
Palladium(II) acetate, Pd(OAc)2
Linear Formula:
Pd(OCOCH3)2
CAS Number:
Molecular Weight:
224.51
Beilstein:
6086766
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.23

Quality Level

Assay

99.98% trace metals basis

form

powder

reaction suitability

core: aluminum
reagent type: catalyst

mp

216.3-223.7 °C (dec.)

SMILES string

CC(O[Pd]OC(C)=O)=O

InChI

1S/2C2H4O2.Pd/c2*1-2(3)4;/h2*1H3,(H,3,4);/q;;+2/p-2

InChI key

YJVFFLUZDVXJQI-UHFFFAOYSA-L

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Application

A non-halogenated palladium(II) complex. It has been used as a catalyst for coupling reactions and as a precursor to prepare palladium-containing materials for heterogeneous catalysis.

Signal Word

Danger

Hazard Statements

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Sens. 1A

Storage Class Code

11 - Combustible Solids

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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    If available for a given product, the recommended re-test date or the expiration date can be found on the Certificate of Analysis.

  2. How do I get lot-specific information or a Certificate of Analysis?

    The lot specific COA document can be found by entering the lot number above under the "Documents" section.

  3. What is the solubility of Product 379875, Palladium (II) acetate?

    It is soluble in chloroform and acetone.  It will decompose in hydrochloric acid.  It is insoluble in water.

  4. What is the melting point of Product 379875, Palladium (II) acetate?

    The melting point of this product is approximately 680 deg C. 

  5. Is Product 379875, Palladium (II) acetate, really 99.98% pure?

    The purity of 99.98% is not the actual chemical purity, but rather the purity based on trace metal content.  A maximum of 300ppm total metallic impurities would be allowed.

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Palladium-catalyzed synthesis of benzofurans and coumarins from phenols and olefins.
Upendra Sharma et al.
Angewandte Chemie (International ed. in English), 52(48), 12669-12673 (2013-10-16)
Hu Kang et al.
Journal of the American Chemical Society, 128(18), 6194-6205 (2006-05-04)
A novel type of "X-shaped" two-dimensional electro-optic (EO) chromophore with extended conjugation has been synthesized and characterized. This chromophore is found to exhibit a remarkably blue-shifted optical maximum (357 nm in CH(2)Cl(2)) while maintaining a very large first hyperpolarizability (beta).
Upendra Sharma et al.
Angewandte Chemie (International ed. in English), 53(44), 11895-11899 (2014-09-11)
A palladium-catalyzed dehydrogenative coupling between diarylamines and olefins has been discovered for the synthesis of substituted indoles. This intermolecular annulation approach incorporates readily available olefins for the first time and obviates the need of any additional directing group. An ortho palladation
Jujjuri, S.; et al.
J. Catal., 239 (2), 486-500 (2006)
Xu, J.; et al.
Journal of Nanoparticle Research, 7 (4-5), 449-467 (2005)

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