380415
Trimethyl(phenoxy)silane
97%
Synonym(s):
Phenoxy(trimethyl)silane, Phenyl trimethylsilyl ether
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About This Item
Linear Formula:
C6H5OSi(CH3)3
CAS Number:
Molecular Weight:
166.29
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
216-211-8
Beilstein/REAXYS Number:
1905943
MDL number:
Assay:
97%
Form:
liquid
InChI key
OJAJJFGMKAZGRZ-UHFFFAOYSA-N
InChI
1S/C9H14OSi/c1-11(2,3)10-9-7-5-4-6-8-9/h4-8H,1-3H3
SMILES string
C[Si](C)(C)Oc1ccccc1
assay
97%
form
liquid
density
0.92 g/mL at 25 °C (lit.)
General description
Trimethyl(phenoxy)silane is a trimethylsilyl protected alcohol. Direct lateral zincation (DlZn) of trimethyl(phenoxy)silane has been reported. Dielectric studies of phenoxysilane-phenol binary systems has been reported.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
3 - Flammable liquids
wgk
WGK 3
flash_point_f
105.8 °F - closed cup
flash_point_c
41 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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Trimethylsilyl Protection of Alcohols Over Phosphorus Pentoxide Supported on Silica Gel.
Shaterian HR, et al.
Phosphorus, Sulfur, and Silicon and the Related Elements, 186(7), 1604-1611 (2011)
STUDIES ON ALCOXYSILANE-ALCOHOL AND PHENOXYSILANE-PHENOL BINARY SYSTEMS.
Nagy J, et al.
Chemical Engineering Journal, 15(3), 155-167 (1971)
Eva Hevia et al.
Chemical communications (Cambridge, England), (22)(22), 3240-3242 (2009-07-10)
A new application of zincate [(THF)Li(TMP)(tBu)Zn(tBu)] (1) in alkali-metal mediated zincation (AMMZn) is reported by isolating and structurally defining the first intermediates of direct lateral zincation (DlZn) of trimethyl(phenoxy)silane (2) both of which adopt novel six-element {ZnCSiOLiN} ring structures.
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