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Merck
CN

39056

1-Ethyl-3-methylimidazolium bis(pentafluoroethylsulfonyl)imide

≥97.0% (H-NMR)

Synonym(s):

EMIMBeTi

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About This Item

Empirical Formula (Hill Notation):
C10H11F10N3O4S2
CAS Number:
Molecular Weight:
491.33
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
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InChI

1S/C6H11N2.C4F10NO4S2/c1-3-8-5-4-7(2)6-8;5-1(6,7)3(11,12)20(16,17)15-21(18,19)4(13,14)2(8,9)10/h4-6H,3H2,1-2H3;/q+1;-1

SMILES string

CCn1cc[n+](C)c1.FC(F)(F)C(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)C(F)(F)F

InChI key

SUDHVXIPIDQEIT-UHFFFAOYSA-N

assay

≥97.0% (H-NMR)

impurities

≤0.5% water

Application

1-Ethyl-3-methylimidazolium bis(pentafluoroethylsulfonyl)imide can be used:
  • As a model ionic liquid in the preparation of supported ionic liquid membranes (SILMs), which are employed in the studies of CO2 and N2 gas permeation.
  • In the studies of solubility and absorption of 1,1,1,2-tetrafluoroethane, difluoromethane, and fluorinated ethanes in ionic liquids.
  • As a medium for the electro-polymerization of pyrrole based monomers to yield N-(methyl)phenyl polypyrroles.

Physical form

fluorinated, hydrophobic ionic liquid

Other Notes

Novel ionic liquid which is exremely hydrophobic, has improved thermal stability and shows no reactivity towards water or air

Legal Information

Product protected by U.S. Patent 5,827,602 assigned to Covalent Associates, Inc. Woburn, Ma, USA

Storage Class

12 - Non Combustible Liquids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves


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Growth of N-substituted polypyrrole layers in ionic liquids: Synthesis and its electrochromic properties
Ahmad S, et al.
Solar Energy Materials and Solar Cells, 99(2), 95-100 (2012)
Solubility and diffusivity of difluoromethane in room-temperature ionic liquids
Shiflett MB, et al.
Journal of Chemical and Engineering Data, 51(2), 483-495 (2006)
Gaseous absorption of fluorinated ethanes by ionic liquids
Liu X, et al.
Fluid Phase Equilibria, 405(2), 1-6 (2015)
Exploring the effect of fluorinated anions on the CO2/N2 separation of supported ionic liquid membranes
Gouveia ASL, et al.
Physical Chemistry Chemical Physics, 19(42), 28876-28884 (2017)
Solubility and diffusivity of 1, 1, 1, 2-tetrafluoroethane in room-temperature ionic liquids
Shiflett MB, et al.
Fluid Phase Equilibria, 242(2), 220-232 (2006)

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