393193
Hydrocinnamaldehyde
technical grade, 90%
Synonym(s):
3-Phenylpropionaldehyde
Sign In to View Organizational & Contract Pricing.
Select a Size
About This Item
Linear Formula:
C6H5CH2CH2CHO
CAS Number:
Molecular Weight:
134.18
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
203-211-8
Beilstein/REAXYS Number:
1071910
MDL number:
Assay:
90%
Form:
liquid
InChI key
YGCZTXZTJXYWCO-UHFFFAOYSA-N
InChI
1S/C9H10O/c10-8-4-7-9-5-2-1-3-6-9/h1-3,5-6,8H,4,7H2
SMILES string
[H]C(=O)CCc1ccccc1
grade
technical grade
assay
90%
form
liquid
impurities
<5% 3-phenyl-1-propanol
Quality Level
bp
97-98 °C/12 mmHg (lit.)
density
1.019 g/mL at 25 °C (lit.)
functional group
aldehyde, phenyl
Looking for similar products? Visit Product Comparison Guide
Related Categories
General description
Hydrocinnamaldehyde is C=C double bond hydrogenated cinnamaldehyde. It has been synthesized by the selective hydrogenation of C=C double bond of cinnamaldehyde by various methods. Hydrocinnamaldehyde and nitromethane undergoes Henry reaction to form nitroaldols. The C1 and C3 position labelled with 13C of hydrocinnamaldehyde was subjected to mass spectrometry and the fragmentation pattern was elucidated.
Application
Hydrocinnamaldehyde may be used in the synthesis of the following:
- 2-Chloro hydrocinnamaldehyde by α-chlorination.
- Mixture of homopropargyl alcohols by kinetic resolution-allenylboration reactions.
- Mixture of syn- and anti-β-hydroxyallylsilanes by hydroboration of allenylsilane.
- (2S)-2-Hydroxy-4-phenylbutanenitrile by catalytic asymmetric cyanosilylation.
- Cinnamaldehyde by dehydrogenation reaction using Pd(TFA)2/4,5-diazafluorenone catalyst.
Storage Class
10 - Combustible liquids
wgk
WGK 2
flash_point_f
203.0 °F - closed cup
flash_point_c
95 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Regulatory Information
新产品
This item has
Choose from one of the most recent versions:
Already Own This Product?
Find documentation for the products that you have recently purchased in the Document Library.
Andy S Tsai et al.
Organic letters, 15(7), 1568-1571 (2013-03-15)
A chiral phosphoric acid catalyzed kinetic resolution/allenylboration of racemic allenylboronates with aldehydes is described. Allenylboration of aldehydes with 2.8 equiv of allenylboronate (±)-1 in the presence of 10 mol % of catalyst (R)-2 provided anti-homopropargyl alcohols 3 in 83-95% yield
Ming Chen et al.
Organic letters, 13(8), 1992-1995 (2011-03-18)
The kinetic hydroboration of allenylsilane 5 with ((d)Ipc)(2)BH at -40 °C provides allylborane 9Z with ≥12:1 selectivity. When the hydroboration is performed at temperatures above -40 °C, 9Z isomerizes to the thermodynamically more stable allylborane 9E with >20:1 selectivity. Subsequent
Influence of Preparation Modes on Pt-Ni/CNTs Catalysts Used in the Selective Hydrogenation of Cinnamaldehyde to Hydrocinnamaldehyde.
Li Y, et al
Catalysis Letters, 126(3-4), 280-285 (2008)
Carbon nanofiber supported palladium catalyst for liquid-phase reactions: An active and selective catalyst for hydrogenation of cinnamaldehyde into hydrocinnamaldehyde.
Pham-Huu C, et al
J. Mol. Catal. A: Chem., 170(1), 155-163 (2001)
Enantioselective henry reactions under dual Lewis acid/amine catalysis using chiral amino alcohol ligands.
Claudio Palomo et al.
Angewandte Chemie (International ed. in English), 44(25), 3881-3884 (2005-05-14)
Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.
Contact Technical Service