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Merck
CN

393258

Bis(2-carbopentyloxy-3,5,6-trichlorophenyl) oxalate

technical grade

Synonym(s):

CPPO

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About This Item

Linear Formula:
[CO2C6H(Cl)3CO2(CH2)4CH3]2
CAS Number:
75203-51-9
Molecular Weight:
677.18
EC Number:
278-124-1
MDL number:
MFCD00012038
UNSPSC Code:
12352103
PubChem Substance ID:
57649894
NACRES:
NA.23

Key Documents

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grade

technical grade

Assay

≥96.5% (by AgNO3, titration)

form

solid

mp

76-80 °C (lit.)

SMILES string

CCCCCOC(=O)c1c(Cl)cc(Cl)c(Cl)c1OC(=O)C(=O)Oc2c(Cl)c(Cl)cc(Cl)c2C(=O)OCCCCC

InChI

1S/C26H24Cl6O8/c1-3-5-7-9-37-23(33)17-13(27)11-15(29)19(31)21(17)39-25(35)26(36)40-22-18(14(28)12-16(30)20(22)32)24(34)38-10-8-6-4-2/h11-12H,3-10H2,1-2H3

InChI key

PURKHUDOTFUVNG-UHFFFAOYSA-N

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General description

Bis(2-carbopentyloxy-3,5,6-trichlorophenyl) oxalate is a peroxyoxalate based material that is used as in chemiluminescent dye which can further be utilized as a detection method for liquid phase analysis. It can be solubilized in organic solvents to achieve high quantum efficiencies and produce a strong chemiluminescent blue light.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCG3840
MKBM8409V
12001HO
08617AG
04013LF

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Chemiluminescent properties of blue fluorophores containing naphthalene unit.
Cheon JW, et al.
Dyes and Pigments, 61(1), 23-30 (2004)
Chemiluminescent properties of copolyesters containing red and blue chromophores.
Lee CW, et al.
Synthetic Metals, 126(1), 97-104 (2002)
Improved microfluidic chip-based sequential-injection trapped-droplet array liquid-liquid extraction system for determination of aluminium.
Shen H and Fang Q
Talanta, 77(1), 269-272 (2008)
Thin-film organic photodiodes as integrated detectors for microscale chemiluminescence assays.
Hofmann O, et al.
Sensors and Actuators B, Chemical, 106(2), 878-884 (2005)

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