394378
4-Bromo-2,6-di-tert-butylphenol
98%
Synonym(s):
2,6-Di-tert-butyl-4-bromophenol, 4-Bromo-2,6-bis(1,1-dimethylethyl)phenol, 4-Hydroxy-3,5-di(tert-butyl)bromobenzene
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About This Item
Linear Formula:
BrC6H2[C(CH3)3]2OH
CAS Number:
Molecular Weight:
285.22
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
214-521-8
Beilstein/REAXYS Number:
2051052
MDL number:
Assay:
98%
Form:
solid
assay
98%
form
solid
mp
78-83 °C (dec.) (lit.)
functional group
bromo
SMILES string
CC(C)(C)c1cc(Br)cc(c1O)C(C)(C)C
InChI
1S/C14H21BrO/c1-13(2,3)10-7-9(15)8-11(12(10)16)14(4,5)6/h7-8,16H,1-6H3
InChI key
SSQQUEKFNSJLKX-UHFFFAOYSA-N
General description
4-Bromo-2,6-di-tert-butylphenol is a 4-substituted-2,6-di-tert-butylphenol. It is synthesized by the bromination of 2,6-di-tert-butylphenol. The structure was confirmed by 1H NMR. Its photolysis reaction in benzene solution has been investigated. The photochemical reaction of 4-bromo-2,6-di-tert-butylphenol single crystals doped with 2,6-di-tert-butyl-p-quinone has been studied by EPR spectroscopy.
Application
4-Bromo-2,6-di-tert-butylphenol may be used in the following studies:
- As a terminating comonomer phenol in the phase transfer catalyzed (PTC) polymerization of 4-bromo-2,6-dimethylphenol.
- Synthesis of 1,1-[1,10-decanediylbis(oxy)]bis[(2,6-ditertbutyl-4-bromo)benzene], a monomer, which forms poly(p-phenylenevinylene) derivatives by reaction with 1,10-dibromodecane.
- As a reactant in the synthesis of 2,6-di-tert-butyl-phenolnorbornene (NArOH), a norbornene comonomer bearing an antioxidant hindered phenol.
- As a catalyst with methyl aluminium to form methylaluminum bis(4-bromo-2,6-di-tert-butylphenoxide) (MABR) which may be utilized for the transformation of various epoxides to carbonyl compounds.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
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Blue light-emitting poly (p-phenylenevinylene) derivatives containing alternating conjugated segments and aliphatic spacers.
Mpallas JG, et al.
Journal of Polymer Science Part A: Polymer Chemistry, 41(8), 1091-1098 (2003)
Effect of donor and acceptor on the mechanism of a photochemical reaction in doped single crystals for radical pairs in 4-bromo-2, 6-di-tert-butylphenol single crystal doped with 2, 6-di-tert-butyl-p-quinone.
Tipikin DS, et al.
Kinetics and Catalysis, 42(2), 246-250 (2001)
An efficient, catalytic procedure for epoxide rearrangement.
Maruoka K, et al.
Tetrahedron Letters, 30(41), 5607-5610 (1989)
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 394378-100G | 04061832280011 |
| 394378-25G | 04061832280028 |