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Merck
CN

397156

Pentadecafluorotriethylamine

96%

Synonym(s):

Perfluorotriethylamine, Tris(pentafluoroethyl)amine

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About This Item

Linear Formula:
N(CF2CF3)3
CAS Number:
359-70-6
Molecular Weight:
371.05
EC Number:
206-632-5
UNSPSC Code:
12352100
PubChem Substance ID:
24864686
Beilstein/REAXYS Number:
1813672
MDL number:
MFCD00166270

Key Documents

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vapor pressure

2.15 psi ( 20 °C)

assay

96%

refractive index

n20/D 1.262 (lit.)

bp

68-69 °C/743 mmHg (lit.)

density

1.736 g/mL at 25 °C (lit.)

SMILES string

FC(F)(F)C(F)(F)N(C(F)(F)C(F)(F)F)C(F)(F)C(F)(F)F

InChI

1S/C6F15N/c7-1(8,9)4(16,17)22(5(18,19)2(10,11)12)6(20,21)3(13,14)15

InChI key

CBEFDCMSEZEGCX-UHFFFAOYSA-N

General description

Pentadecafluorotriethylamine (Perfluorotriethylamine, Tris(pentafluoroethyl)amine) is a non-polar organo fluorine compound. Its various physical parameters have been reported. It is an efficient substitute of reaction medium for the Lewis acid mediated reactions. Pyrolysis of perfluorotriethylamine was studied to investigate its thermal behavior in firefighting. Perfluorinated N-ethylpyrrolidine has been identified as the major decomposition product by GC-MS analysis. Production of long-lived microbubbles (50-100μm) in perfluorotriethylamine has been studied.

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
BCBL5603V
1412894V
1412894
08908KE
U19618

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The behavior of bubbles in perfluorotriethylamine under the effect of strong electric fields.
Korobeinikov SM, et al.
High Temperature, 39(6), 821-825 (2001)
An efficient high-yield synthesis for perfluorinated tertiary alkyl amines.
Felling KW and Lagow RJ.
Journal of Fluorine Chemistry, 123(2), 233-236 (2003)
Thermal decomposition of halon alternatives.
Yamamoto T, et al.
Chemosphere, 35(3), 643-654 (1997)
Organic reactions without an organic medium. Utilization of perfluorotriethylamine as a reaction medium.
Nakano H and Kitazume T.
Green Chemistry, 1(1), 21-22 (1999)

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