398845
Lead(IV) acetate
≥99.99% trace metals basis
Synonym(s):
Lead tetraacetate, Pb(acac)4
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About This Item
Linear Formula:
Pb(CH3CO2)4
CAS Number:
Molecular Weight:
443.38
EC Number:
208-908-0
UNSPSC Code:
12352300
PubChem Substance ID:
Beilstein/REAXYS Number:
3595640
MDL number:
assay
≥99.99% trace metals basis
reaction suitability
core: lead, reagent type: catalyst
SMILES string
CC(=O)O[Pb](OC(C)=O)(OC(C)=O)OC(C)=O
InChI
1S/4C2H4O2.Pb/c4*1-2(3)4;/h4*1H3,(H,3,4);/q;;;;+4/p-4
InChI key
JEHCHYAKAXDFKV-UHFFFAOYSA-J
Application
Smoothly induces the addition of difluorodiiodomethane to alkenes and alkynes.
signalword
Danger
Hazard Classifications
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Repr. 1A - STOT RE 2
Storage Class
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
Regulatory Information
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Li, A-R. Chen, Q-Y.
Synthesis, 1481-1481 (1997)
Luis Moreno-Osorio et al.
Magnetic resonance in chemistry : MRC, 45(11), 993-996 (2007-09-19)
Two naturally occurring 11-nordrimanes were synthesized, and their (1)H and (13)C NMR spectra were unambiguously assigned in full for the first time.
Hidehito Urata et al.
Chemical & pharmaceutical bulletin, 56(11), 1611-1612 (2008-11-05)
The first chemical synthesis of two metabolites ((1R,2S,5R,6S)-6-(3,4-dihydroxyphenyl)-2-(3,4-methylenedioxyphenyl)-3,7-dioxabicyclo[3,3,0]octane (SC-1) and (1R,2S,5R,6S)-2,6-bis(3,4-dihydroxyphenyl)-3,7-dioxabicyclo[3,3,0]octane (SC-2)) of sesamin was achieved by a simple two-step approach from sesamin. The approach consists of acetoxylation of the methylenedioxy moiety(ies) with lead(IV) tetraacetate and acid hydrolysis of the