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Merck
CN

398845

Lead(IV) acetate

≥99.99% trace metals basis

Synonym(s):

Lead tetraacetate, Pb(acac)4

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About This Item

Linear Formula:
Pb(CH3CO2)4
CAS Number:
546-67-8
Molecular Weight:
443.38
EC Number:
208-908-0
UNSPSC Code:
12352300
PubChem Substance ID:
24864770
Beilstein/REAXYS Number:
3595640
MDL number:
MFCD00008693

Key Documents

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Product Name

Lead(IV) acetate, ≥99.99% trace metals basis

InChI key

JEHCHYAKAXDFKV-UHFFFAOYSA-J

InChI

1S/4C2H4O2.Pb/c4*1-2(3)4;/h4*1H3,(H,3,4);/q;;;;+4/p-4

SMILES string

CC(=O)O[Pb](OC(C)=O)(OC(C)=O)OC(C)=O

assay

≥99.99% trace metals basis

reaction suitability

core: lead
reagent type: catalyst

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Application

Smoothly induces the addition of difluorodiiodomethane to alkenes and alkynes.

signalword

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Repr. 1A - STOT RE 2

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
MKBG2078V
MKBB6116
18510KU
16828BI
12620AE

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Li, A-R. Chen, Q-Y.
Synthesis, 1481-1481 (1997)
S Mårtensson et al.
European journal of biochemistry, 258(2), 603-622 (1999-01-05)
Oligosaccharide alditols were released from bovine submaxillary mucin by alkaline borohydride treatment. The fractions containing smaller neutral oligosaccharides were separated by HPLC, to give, in the mono-, di- and trisaccharide-alditol sizes, 19 different structures, in addition to three fucosylated tetrasaccharide
N S Kumar et al.
Carbohydrate research, 291, 109-114 (1996-09-23)
Oxidative decarboxylation of peracetylated welan gum (S-130) with lead tetraacetate resulted in selective cleavage of the glucuronosidic linkages. Products of the degradation were reduced with sodium borohydride, O-deacetylated, and fractionated. Polymeric and oligomeric fractions were separated and analysed by 1H
B H Jennings et al.
Steroids, 37(1), 7-22 (1981-01-01)
A comparative study was made of the reactions of 5-bromo-3 beta, 6 beta-dihydroxy-5 alpha-androstan-17-one 3-acetate (1) with lead tetraacetate alone and in the presence of iodine in both high intensity visible light and in total darkness using a variety of
[A combined carbohydrate immunocytochemical technic for localization of glycogen in the pancreatic islands of steroid diabetic rats].
R Graf et al.
Acta histochemica. Supplementband, 25, 61-62 (1982-01-01)
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