399191
Rhodium(II) trifluoroacetate dimer
Synonym(s):
Trifluoroacetic acid rhodium(II) salt dimer
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About This Item
Linear Formula:
[(CF3COO)2Rh]2
CAS Number:
Molecular Weight:
657.87
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
InChI
1S/4C2HF3O2.2Rh/c4*3-2(4,5)1(6)7;;/h4*(H,6,7);;/q;;;;2*+2/p-4
SMILES string
FC(F)(F)C(=O)O[Rh]OC(=O)C(F)(F)F.FC(F)(F)C(=O)O[Rh]OC(=O)C(F)(F)F
InChI key
PQEXTYUESSEHKW-UHFFFAOYSA-J
Quality Level
reaction suitability
reagent type: catalyst
Application
Used in the preparation of isomerically pure α,β-unsaturated carbonyl compounds and the preparation of building blocks for one-, two-, and three-dimensional molecular solids.
Other Notes
Contains a trace amount of rhodium acetate
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
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A Convenient Method for the Preparation of (Z)-alpha,beta-Unsaturated Carbonyl Compounds.
Douglass F. Taber et al.
The Journal of organic chemistry, 61(8), 2908-2910 (1996-04-19)
Li-Feng Mao et al.
Inorganic chemistry, 35(11), 3183-3187 (1996-05-22)
The complexes trans-[MI(2)(CNC(6)H(4)-CN-4)(2)], (M = Pd and Pt), trans-[FeI(2)L(4)] (L = CNC(6)H(4)-CN-4 and CNC(6)H(2)-Me(2)-2,6-CN-4), and [Mn(CNC(6)H(4)-CN-4)(6)][SO(3)CF(3)] were prepared. The compounds are thermally stable up to 230 degrees C or higher. The molecular structure of trans-[FeI(2)(CNC(6)H(4)-CN-4)(4)] was determined by X-ray crystallography:
Ligand-induced fate of embryonic species in the shape-controlled synthesis of rhodium nanoparticles.
Adam J Biacchi et al.
ACS nano, 9(2), 1707-1720 (2015-01-30)
The shapes of noble metal nanoparticles directly impact their properties and applications, including in catalysis and plasmonics, and it is therefore important to understand how multiple distinct morphologies can be controllably synthesized. Solution routes offer powerful capabilities for shape-controlled nanoparticle
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