399418
Benzoin
purified by sublimation, 99.5%
Synonym(s):
α-Hydroxy-α-phenylacetophenone, α-Hydroxybenzyl phenyl ketone, 2-Hydroxy-2-phenylacetophenone
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About This Item
Linear Formula:
C6H5CH(OH)COC6H5
CAS Number:
Molecular Weight:
212.24
Beilstein:
391839
EC Number:
MDL number:
UNSPSC Code:
12162002
Assay
99.5%
purified by
sublimation
bp
194 °C/12 mmHg (lit.)
mp
134-138 °C (lit.)
SMILES string
OC(c1ccccc1)C(=O)c2ccccc2
InChI
1S/C14H12O2/c15-13(11-7-3-1-4-8-11)14(16)12-9-5-2-6-10-12/h1-10,13,15H
InChI key
ISAOCJYIOMOJEB-UHFFFAOYSA-N
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Storage Class Code
11 - Combustible Solids
WGK
WGK 2
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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Tsuneomi Kawasaki et al.
Angewandte Chemie (International ed. in English), 50(35), 8131-8133 (2011-07-16)
Trigger happy: chiral oxygen isotopomers of hydrobenzoin ([(18)O](R)-1 and [(18)O](S)-1) acted as chiral triggers to induce the enantioselective addition of iPr(2)Zn to pyrimidine-5-carbaldehyde. An extremely small chiral influence arising from the presence of the oxygen isotope ((18)O) is amplified through
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Angewandte Chemie (International ed. in English), 51(47), 11686-11698 (2012-10-18)
N-Heterocyclic carbene (NHC) catalyzed transformations have emerged as powerful tactics for the construction of complex molecules. Since Stetter's report in 1975 of the total synthesis of cis-jasmon and dihydrojasmon by using carbene catalysis, the use of NHCs in total synthesis
Structures and reactivities of O-methylated Breslow intermediates.
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Angewandte Chemie (International ed. in English), 51(41), 10408-10412 (2012-09-13)
Serge Droux et al.
Chirality, 23 Suppl 1, E105-E109 (2011-10-15)
We report here the application of subcritical water in chiral separations on two popular polysaccharide chiral stationary phases (CSPs): Chiralpak AD and Chiralcel OD. The behavior of these two CSPs was studied under reversed phase conditions at room temperature to
Chromatograms
application for HPLC
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