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Merck
CN

400149

(1R,2R)-1,2-Dicyclohexyl-1,2-ethanediol

95%

Synonym(s):

(1R,2R)-1,2-Dicyclohexylethylene glycol

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About This Item

Linear Formula:
[C6H11CH(OH)-]2
CAS Number:
Molecular Weight:
226.36
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352001
MDL number:
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InChI

1S/C14H26O2/c15-13(11-7-3-1-4-8-11)14(16)12-9-5-2-6-10-12/h11-16H,1-10H2/t13-,14-/m1/s1

SMILES string

O[C@H](C1CCCCC1)[C@H](O)C2CCCCC2

InChI key

CKHLARJSOMXDKL-ZIAGYGMSSA-N

assay

95%

optical activity

[α]20/D −2.2°, c = 0.8 in chloroform

Application

C2 symmetric chiral diol with versatile applications as a chiral auxiliary, building block, and chiral ligand. Chiral auxiliary for preparing highly diastereomerically pure alkyl boronates.

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

Regulatory Information

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Chemische Berichte, 122, 1783-1783 (1989)
Stolle, A. et al.
Tetrahedron Letters, 35, 3521-3521 (1994)
Ho, O.C. et al.
Organometallics, 14, 2855-2855 (1995)
Pichon, M. Figadere, B.
Tetrahedron Asymmetry, 7, 927-927 (1996)
Matteson, D.S. Man, H.-W.
The Journal of Organic Chemistry, 59, 5734-5734 (1994)

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