401439
Zinc perchlorate hexahydrate
Synonym(s):
Perchloric acid zinc hydrate
Sign In to View Organizational & Contract Pricing.
Select a Size
Change View
About This Item
Linear Formula:
Zn(ClO4)2·6H2O
CAS Number:
Molecular Weight:
372.38
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
237-122-0
MDL number:
Form:
crystals and lumps
form
crystals and lumps
Quality Level
reaction suitability
core: zinc, reagent type: oxidant
SMILES string
O.O.O.O.O.O.[Zn++].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O
InChI
1S/2ClHO4.6H2O.Zn/c2*2-1(3,4)5;;;;;;;/h2*(H,2,3,4,5);6*1H2;/q;;;;;;;;+2/p-2
InChI key
PADPILQDYPIHQQ-UHFFFAOYSA-L
General description
Zinc perchlorate hexahydrate is a hexahydrate salt of zinc widely used as an oxidation reagent and catalyst in various organic transformations. It also finds application in the field of rechargeable batteries.
Application
Zinc perchlorate hexahydrate can be used as a catalyst:
- For acylation of electron-deficient phenols, sterically hindered alcohols and amines.
- For the synthesis of 2-hydroxy sulfides by the opening of epoxide rings with thiols.
- For solvent‐free condensation of carboxylic acids with alcohols.
- An electrolyte for aqueous Zinc batteries.
- A precursor for the synthesis of highly fluorescent ZnSe quantumdots.
signalword
Danger
hcodes
Hazard Classifications
Ox. Sol. 2 - Skin Corr. 1B
Storage Class
5.1A - Strongly oxidizing hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Choose from one of the most recent versions:
Already Own This Product?
Find documentation for the products that you have recently purchased in the Document Library.
Articles
Colloidal quantum dots (CQDs) are semiconducting crystals of only a few nanometers (ca. 2–12 nm) coated with ligand/surfactant molecules to help prevent agglomeration.
Zinc perchlorate hexahydrate [Zn(ClO4)2?6H2O] as acylation catalyst for poor nucleophilic phenols, alcohols and amines: Scope and limitations
Shivani, et al.
J. Mol. Catal. A: Chem., 264, 208-213 (2007)
Highly Efficient Solvent-Free Condensation of Carboxylic Acids with Alcohols Catalysed by Zinc Perchlorate Hexahydrate, Zn(ClO4)2?6 H2O
G Bartoli, et al.
Advanced Synthesis & Catalysis, 347, 33-38 (2005)
Photo-assisted synthesis of highly fluorescent ZnSe(S) quantum dots in aqueous solution
Guo-Yu Lan, et al.
Journal of Materials Chemistry, 17, 2661-2666 (2007)
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 401439-100G | 04061831985474 |
| 401439-500G | 04061831985481 |