403083
1,3-Dibromoadamantane
99%
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About This Item
Empirical Formula (Hill Notation):
C10H14Br2
CAS Number:
Molecular Weight:
294.03
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Product Name
1,3-Dibromoadamantane, 99%
InChI
1S/C10H14Br2/c11-9-2-7-1-8(4-9)5-10(12,3-7)6-9/h7-8H,1-6H2/t7-,8+,9+,10-
SMILES string
Br[C@]12C[C@@H]3C[C@H](C1)C[C@@](Br)(C3)C2
InChI key
HLWZKLMEOVIWRK-FIRGSJFUSA-N
assay
99%
form
powder
mp
108-110 °C (lit.)
functional group
bromo
Quality Level
Related Categories
Application
1,3-Dibromoadamantane may be used in the preparation of 1,3-bis(phenyldimethylsilyl)adamantine.
General description
1,3-Dibromoadamantane is reported to react with diphenylphosphide ions (Ph2P-) under photostimulation by the SRN1 mechanism. The viscosity-dependent retarding effect of 1,3-dibromoadamantane in highly viscous polymeric chlorotrifluoroethene has been studied by 13C NMR relaxation measurements. Preparation of 1,3-dibromoadamantane via dibromination of adamantine has been reported.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Regulatory Information
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Lienin et al.
Journal of magnetic resonance (San Diego, Calif. : 1997), 131(2), 184-190 (1998-05-08)
The viscosity-dependent retarding effect of a polymeric solvent on the rotation of small solute molecules is investigated by 13C NMR relaxation measurements. It is found that the relaxation data of 1,3-dibromoadamantane in highly viscous polymeric chlorotrifluoroethene can be explained neither
Selective dibromination of adamantane.
Talaty ER, et al.
J. Chem. Soc. Sect. C, 1902-1903 (1968)
Preparation of 1-silyl-and 1, 3-disilyl-adamantanes.
Pai Y-M, et al.
Journal of Organometallic Chemistry, 270(3), 271-275 (1984)
Reactions of 1, 3-dihaloadamantanes with diphenylphosphide ions by the SRN1 mechanism. Competition between intermolecular and intramolecular electron transfer reactions.
Lukach AE, et al.
Journal of Physical Organic Chemistry, 7(11), 610-614 (1994)
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