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404284

Benzyl phenyl ether

Name: Benzyl phenyl ether
Brand: ALDRICH

98%

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About This Item

Linear Formula:

C₆H₅CH₂OC₆H₅

CAS Number:

946-80-5

Molecular Weight:

184.23

NACRES:

NA.22

PubChem Substance ID:

24865236

UNSPSC Code:

12352100

MDL number:

MFCD00020660

Assay:

98%

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Properties

assay

98%

bp

286-287 °C (lit.)

mp

39-41 °C (lit.)

functional group

phenoxy, phenyl

SMILES string

C(Oc1ccccc1)c2ccccc2

InChI

1S/C13H12O/c1-3-7-12(8-4-1)11-14-13-9-5-2-6-10-13/h1-10H,11H2

InChI key

BOTNYLSAWDQNEX-UHFFFAOYSA-N

Description

General description

Benzyl phenyl ether is a reactive organic oxygenate, containing ether as functional group, present in subbituminous and bituminous coals. It reacts with aluminium bromide in chlorobenzene solution to afford a mixture of phenol, o-benzyl phenol and dichlorodiphenylmethane. It is a useful as model compound in catalytic chemistry to represent the a-O4 ether bond in lignin and coal. It contains a weak ether bond of 234kJ/mol and belongs to the most thermo-labile compounds in lignin and low rank coal. Influence of alkali carbonates, common additives in biomass conversion, on the reaction pathways of BPE in superheated water has been reported. Cesium-exchanged heteropolyacid catalyzed decomposition of benzyl phenyl ether to aromatics has been investigated. Photo-Claisen rearrangements of benzyl phenyl ether was investigated in cation-exchanged Y zeolites and polyethylenes of differing crystallinities.

pictograms

GHS07

signalword

Warning

hcodes

H315,H319,H335

pcodes

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Understanding the influence of active (zeolite) and passive (polyethylene) reaction cages on photo-Claisen rearrangements of aryl benzyl ethers.

Gu W, et al.

Langmuir, 16(17), 6977-6981 (2000)

Effects of Sugars, Furans, and their Derivatives on Hydrodeoxygenation of Biorefinery Lignin-Rich Wastes to Hydrocarbons.

Hongliang Wang et al.

ChemSusChem, 11(15), 2562-2568 (2018-07-04)

Hydrodeoxygenation of biorefinery lignin-rich wastes to jet fuel hydrocarbons offers a significant opportunity for enhancing the overall operational efficiency, carbon conversion efficiency, economic viability, and sustainability of biofuels production. However, these wastes usually mainly contain lignin with sugars, furans, and

Catalytic decomposition of benzyl phenyl ether to aromatics over cesium-exchanged heteropolyacid catalyst.

Park HW, et al.

Korean Journal of Chemical Engineering, 28(5), 1177-1180 (2011)

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Global Trade Item Number

SKU	GTIN
404284-5G	04061831986747