40577
(S)-1-Octen-3-ol
≥95% (sum of enantiomers, GC)
Synonym(s):
(S)-Matsutake alcohol
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About This Item
Empirical Formula (Hill Notation):
C8H16O
CAS Number:
Molecular Weight:
128.21
MDL number:
UNSPSC Code:
12352002
PubChem Substance ID:
NACRES:
NA.22
Assay
≥95% (sum of enantiomers, GC)
form
liquid
optical purity
enantiomeric ratio: ≥99:1 (GC)
functional group
hydroxyl
SMILES string
CCCCC[C@H](O)C=C
InChI
1S/C8H16O/c1-3-5-6-7-8(9)4-2/h4,8-9H,2-3,5-7H2,1H3/t8-/m1/s1
InChI key
VSMOENVRRABVKN-MRVPVSSYSA-N
Application
(S)-1-Octen-3-ol can be used:
- As an odorant in the study of an olfactory sensory map of the Anopheles gambiae maxillary palp.
- As an intermediate in the synthesis of natural product polyporolide and a prostaglandin named 8-aza-prostaglandin E1.
- As a substrate in the preparation of trienols by reacting with 1-iodo-1,3-dienes using Pd(OAc)2/AgOAc.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2
Storage Class Code
10 - Combustible liquids
WGK
WGK 3
Flash Point(F)
154.4 °F - closed cup
Flash Point(C)
68 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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Characterization of an enantioselective odorant receptor in the yellow fever mosquito Aedes aegypti.
Jonathan D Bohbot et al.
PloS one, 4(9), e7032-e7032 (2009-09-16)
Enantiomers differ only in the left or right handedness (chirality) of their orientations and exhibit identical chemical and physical properties. In chemical communication systems, enantiomers can be differentially active at the physiological and behavioral levels. Only recently were enantioselective odorant
A stereoselective synthesis of the reported structure of polyporolide
Patil PH and Fernandes RA
Royal Society of Chemistry Advances, 5(61), 49189-49194 (2015)
Odor coding in the maxillary palp of the malaria vector mosquito Anopheles gambiae
Lu T, et al.
Current Biology, 17(18), 1533-1544 (2007)
Alan J Grant et al.
PloS one, 6(6), e21785-e21785 (2011-07-09)
1-Octen-3-ol (octenol) is a common attractant released by vertebrates which in combination with carbon dioxide (CO(2)) attracts hematophagous arthropods including mosquitoes. A receptor neuron contained within basiconic sensilla on the maxillary palps of adult mosquitoes responds selectively to 1-octen-3-ol. Recently
Xiao-Gang Wang et al.
The Journal of organic chemistry, 78(18), 9488-9493 (2013-08-21)
We report herein for the first time the enantioselective synthesis of 8-aza-PGE1. The synthesis used the cross olefin metathesis reaction to connect the 5-vinyl-γ-lactam subunit, prepared from (R)-malic acid via the Ley's sulfone-based α-amidalkylation protocol (dr = 6.8:1), with the
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