406554
Diethyl malonimidate dihydrochloride
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About This Item
Linear Formula:
C2H5OC(=NH)CH2C(=NH)OC2H5·2HCl
CAS Number:
Molecular Weight:
231.12
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
InChI
1S/C7H14N2O2.2ClH/c1-3-10-6(8)5-7(9)11-4-2;;/h8-9H,3-5H2,1-2H3;2*1H
SMILES string
Cl.Cl.CCOC(=N)CC(=N)OCC
InChI key
TWUQXVGHXWRUBR-UHFFFAOYSA-N
impurities
<5% ammonium chloride
mp
122 °C (dec.) (lit.)
functional group
amine, ether
Quality Level
Related Categories
Application
Diethyl malonimidate dihydrochloride may be used in the preparation of chiral bis(oxazoline) ligands. It may be used in the preparation of intramolecularly cross-linked urokinase.
Reactant for:
- Preparation of rhenium cyanobis(oxazoline) oxo complexes as enantioselective reduction catalysts
- Synthesis of chiral bis(oxazoline)-copper complexes immobilized by donor-acceptor interactions on insoluble organic supports as reusable catalysts for asymmetric Diels-Alder cycloaddition
- Preparation of nonracemic bis(oxazoline)ruthenium p-cymene complexes and silica-supported analogs as catalysts for the enantioselective transfer hydrogenation of ketones to secondary alcohols
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 3
ppe
dust mask type N95 (US), Eyeshields, Gloves
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Chemical modification of urokinase with bis-imidoesters and properties of the intramolecularly cross-linked enzyme.
Yokoigawa K, et al.
Agricultural and Biological Chemistry, 53(7), 1837-1842 (1989)
New chiral bis (oxazoline) Rh (I)-, Ir (I)-and Ru (II)-complexes for asymmetric transfer hydrogenations of ketones.
Debono N, et al.
Tetrahedron Letters, 45(10), 2235-2238 (2004)
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