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Merck
CN

407518

Julolidine hydrobromide

97%

Synonym(s):

2,3,6,7-Tetrahydro-1H,5H-benzo[ij]quinolizine hydrobromide

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About This Item

Empirical Formula (Hill Notation):
C12H15N · HBr
CAS Number:
83646-41-7
Molecular Weight:
254.17
NACRES:
NA.22
PubChem Substance ID:
24865457
UNSPSC Code:
12352100
MDL number:
MFCD00198009

Key Documents

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Product Name

Julolidine hydrobromide, 97%

InChI

1S/C12H15N.BrH/c1-4-10-6-2-8-13-9-3-7-11(5-1)12(10)13;/h1,4-5H,2-3,6-9H2;1H

SMILES string

Br.C1CN2CCCc3cccc(C1)c23

InChI key

KHWBRFVBPGPEOJ-UHFFFAOYSA-N

assay

97%

form

powder

mp

239-242 °C (lit.)

Quality Level

100

Related Categories

Application

Julolidine hydrobromide may be used in the synthesis of [4-(2,3,6,7-tetrahydro-1H,5H-pyrido[3,2,1-ij]quinolin-9-ylazo)-phenyl]-methanol azodye.

General description

Julolidines are effective auxofluors that are employed in laser dyes and biochemical stains. They are known to be one of the strongest electron-releasing groups due to electronic and steric factors.

pictograms

Skull and crossbonesCorrosion
GHS06,GHS05

signalword

Danger

Hazard Classifications

Acute Tox. 3 Oral - Eye Dam. 1 - Skin Corr. 1B

supp_hazards

EUH014

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
MKBJ1643V
MKBH9159V
96696PJ
04013DE
12426KC

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Synthesis, optical characterization and crystal and molecular X-ray structure of a phenylazojulolidine derivative.
Barbero N, et al.
Dyes and Pigments, 92(3), 1177-1183 (2012)
Synthesis of julolidine derivatives.
Kauffman JM, et al.
Organic preparations and procedures international, 33(6), 603-613 (2001)

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