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407992

N-Methylphthalimide

Name: <I>N</I>-Methylphthalimide
Brand: ALDRICH

98%

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About This Item

Empirical Formula (Hill Notation):

C₉H₇NO₂

CAS Number:

550-44-7

Molecular Weight:

161.16

NACRES:

NA.22

PubChem Substance ID:

24865500

UNSPSC Code:

12352100

EC Number:

208-982-4

MDL number:

MFCD00023063

Assay:

98%

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Properties

Quality Level

100

assay

98%

mp

129-132 °C (lit.)

functional group

imide

SMILES string

CN1C(=O)c2ccccc2C1=O

InChI

1S/C9H7NO2/c1-10-8(11)6-4-2-3-5-7(6)9(10)12/h2-5H,1H3

InChI key

ZXLYYQUMYFHCLQ-UHFFFAOYSA-N

Description

General description

Photoreduction of N-methylphthalimide (NMP) with 2,3-dimethyl-2-butene has been studied. The selective electroreduction of N-methylphthalimide to 3-hydroxy-2-methyl-isoindolin-1-one in ionic liquids and phenol as a proton donor under silent and ultrasonic conditions has been reported. Single electron transfer (SET)-induced photochemical reaction of NMP with silyl enol ether has been investigated. Nitration of NMP is reported to afford “exclusively” 3-nitro-derivative.

Storage Class

11 - Combustible Solids

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Nitration of N-alkylphthalimides.

Williams FJ and Donahue PE.

The Journal of Organic Chemistry, 43(8), 1608-1610 (1978)

Electroreduction of N-methylphthalimide in room temperature ionic liquids under insonated and silent conditions.

Constanza Villagrán et al.

Ultrasonics sonochemistry, 12(6), 423-428 (2005-04-26)

The selective electroreduction N-methylphthalimide to 3-hydroxy-2-methyl-isoindolin-1-one has been performed in ionic liquids using phenol as a proton donor under silent and ultrasonic conditions. A significant increase in the rate of electroreduction is shown using ultrasonic activation and in addition high

Photoreduction of N-methylphthalimide with 2, 3-dimethyl-2-butene. Evidence for reaction through an electron transfer generated ion pair.

Mazzocchi PH and Klingler L.

Journal of the American Chemical Society, 106(24), 7567-7572 (1984)

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Global Trade Item Number

SKU	GTIN
407992-5G	04061831988413